Matches in SemOpenAlex for { <https://semopenalex.org/work/W2034873055> ?p ?o ?g. }
Showing items 1 to 78 of
78
with 100 items per page.
- W2034873055 endingPage "599" @default.
- W2034873055 startingPage "597" @default.
- W2034873055 abstract "2,5-Dimethyl-1,2,3-diazaphosphol (1a) reagiert beim Erwärmen mit Diphenyldiazomethan (2); unter Abspaltung von N2 entsteht durch Addition der Ph2C-Gruppe an die PC-Bindung ein anellierter Phosphiranring (4). Die Abstufung der 1-Reaktivität legt eine primäre Cycloaddition von 2 an 1 unter PC/CN-Verknüpfung nahe. – 5-(Ethoxycarbonyl)-2-phenyl-1,3,4-thiazaphosphol (8) reagiert schon bei Raumtemp. mit 2 u.a. zu dem entsprechenden Bicyclus 9. 2,5-Dimethyl-1,2,3-diazaphosphole (1a) reacts with diphenyldiazomethane (2) on warming; with loss of N2 and addition of the Ph2C group to the PC-bond an anellated phosphirane ring (4) is formed. The order of reactivity of 1 suggests a primary cycloaddition of 2 to 1 with PC and CN linking. – 5-(Ethoxycarbonyl)-2-phenyl-1,3,4-thiazaphosphole (8) reacts with 2 already at room temperature to yield among other products the corresponding bicyclus 9." @default.
- W2034873055 created "2016-06-24" @default.
- W2034873055 creator A5028884218 @default.
- W2034873055 creator A5030074780 @default.
- W2034873055 creator A5063829831 @default.
- W2034873055 creator A5076220878 @default.
- W2034873055 date "1987-04-01" @default.
- W2034873055 modified "2023-09-27" @default.
- W2034873055 title "Die Reaktion von 1,2,3‐Diaza‐ und 1,3,4‐Thiazaphospholen mit Diphenyldiazomethan" @default.
- W2034873055 cites W1592646197 @default.
- W2034873055 cites W2027017785 @default.
- W2034873055 cites W2045024651 @default.
- W2034873055 cites W2047627844 @default.
- W2034873055 cites W2056001183 @default.
- W2034873055 cites W2076522749 @default.
- W2034873055 cites W2096925191 @default.
- W2034873055 cites W2148109098 @default.
- W2034873055 cites W2149495364 @default.
- W2034873055 cites W2151871631 @default.
- W2034873055 cites W2317249972 @default.
- W2034873055 cites W2333579075 @default.
- W2034873055 cites W4232903133 @default.
- W2034873055 doi "https://doi.org/10.1002/cber.19871200421" @default.
- W2034873055 hasPublicationYear "1987" @default.
- W2034873055 type Work @default.
- W2034873055 sameAs 2034873055 @default.
- W2034873055 citedByCount "18" @default.
- W2034873055 countsByYear W20348730552012 @default.
- W2034873055 crossrefType "journal-article" @default.
- W2034873055 hasAuthorship W2034873055A5028884218 @default.
- W2034873055 hasAuthorship W2034873055A5030074780 @default.
- W2034873055 hasAuthorship W2034873055A5063829831 @default.
- W2034873055 hasAuthorship W2034873055A5076220878 @default.
- W2034873055 hasConcept C142724271 @default.
- W2034873055 hasConcept C155647269 @default.
- W2034873055 hasConcept C161790260 @default.
- W2034873055 hasConcept C178790620 @default.
- W2034873055 hasConcept C185592680 @default.
- W2034873055 hasConcept C204787440 @default.
- W2034873055 hasConcept C24961977 @default.
- W2034873055 hasConcept C2776910235 @default.
- W2034873055 hasConcept C2779664164 @default.
- W2034873055 hasConcept C2780378348 @default.
- W2034873055 hasConcept C71240020 @default.
- W2034873055 hasConcept C71924100 @default.
- W2034873055 hasConceptScore W2034873055C142724271 @default.
- W2034873055 hasConceptScore W2034873055C155647269 @default.
- W2034873055 hasConceptScore W2034873055C161790260 @default.
- W2034873055 hasConceptScore W2034873055C178790620 @default.
- W2034873055 hasConceptScore W2034873055C185592680 @default.
- W2034873055 hasConceptScore W2034873055C204787440 @default.
- W2034873055 hasConceptScore W2034873055C24961977 @default.
- W2034873055 hasConceptScore W2034873055C2776910235 @default.
- W2034873055 hasConceptScore W2034873055C2779664164 @default.
- W2034873055 hasConceptScore W2034873055C2780378348 @default.
- W2034873055 hasConceptScore W2034873055C71240020 @default.
- W2034873055 hasConceptScore W2034873055C71924100 @default.
- W2034873055 hasIssue "4" @default.
- W2034873055 hasLocation W20348730551 @default.
- W2034873055 hasOpenAccess W2034873055 @default.
- W2034873055 hasPrimaryLocation W20348730551 @default.
- W2034873055 hasRelatedWork W2031034006 @default.
- W2034873055 hasRelatedWork W2037808278 @default.
- W2034873055 hasRelatedWork W2048303153 @default.
- W2034873055 hasRelatedWork W2049064961 @default.
- W2034873055 hasRelatedWork W2094479206 @default.
- W2034873055 hasRelatedWork W2491300975 @default.
- W2034873055 hasRelatedWork W2949749362 @default.
- W2034873055 hasRelatedWork W2950063136 @default.
- W2034873055 hasRelatedWork W2950731645 @default.
- W2034873055 hasRelatedWork W2951272751 @default.
- W2034873055 hasVolume "120" @default.
- W2034873055 isParatext "false" @default.
- W2034873055 isRetracted "false" @default.
- W2034873055 magId "2034873055" @default.
- W2034873055 workType "article" @default.