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- W2034873516 abstract "The kinetics of the decomposition of β-Pd0.85Ni0.15Hx were determined under isothermal conditions. The experiments were carried out with a suspension of alloy particles in liquid undecane. The rate-limiting process is the solid state transformation taking place at the interface between the hydride and the hydrogen solid solution phase. The activation energy was 78 kJ mol−1; the pre-exponential in the Arrhenius expression is 4.38 × 109 s−1. The results are discussed in terms of the Polanyi-Wigner expression and the activated complex theory. It is proposed that the decomposition proceeds by the conversion of a group of approximately ten whole β phase unit cells to a corresponding group of whole α phase unit cells." @default.
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- W2034873516 date "1991-08-01" @default.
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- W2034873516 title "Decomposition kinetics of palladium nickel hydride" @default.
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- W2034873516 doi "https://doi.org/10.1016/0022-5088(91)90438-a" @default.
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