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• W2034876825 endingPage "1127" @default.
• W2034876825 startingPage "1120" @default.
• W2034876825 abstract "Flaking out: Porous hybrid Cu2O/polypyrrole nanoflakes were synthesized through reductive transformation of CuO nanoplates in the presence of pyrrole. The as-prepared porous hybrid nanostructures exhibited efficient catalytic activity and high stability towards an oxygen reduction reaction in alkaline solution. Porous hybrid Cu2O/polypyrrole nanoflakes have been synthesized from solid CuO nanoplate templates through the pyrrole-induced reductive transformation reaction at elevated temperature. The conversion mechanism involves the reductive transformation of CuO to Cu2O and the in situ oxidative polymerization of pyrrole to polypyrrole. In addition, the morphology of the as-converted nanohybrids depends on the shape of the CuO precursors. The strategy enables us to transform single-crystalline CuO nanosheets into hollow hybrid Cu2O/polypyrrole nanoframes. The ability to transform CuO and an organic monomer into porous hybrid materials of conducting polymer and Cu2O with macrosized morphological retention opens up interesting possibilities to create novel nanostructures. Electrochemical examinations show that these porous hybrid Cu2O/polypyrrole nanostructures exhibit efficient catalytic activity towards oxygen reduction reaction (ORR), excellent methanol tolerance ability, and catalytic stability in alkaline solution, thus making them promising nonprecious-metal-based catalysts for ORR in alkaline fuel cells and metal–air batteries. 1" @default.
• W2034876825 created "2016-06-24" @default.
• W2034876825 creator A5020956181 @default.
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• W2034876825 creator A5078327202 @default.
• W2034876825 creator A5085752584 @default.
• W2034876825 date "2013-04-22" @default.
• W2034876825 modified "2023-09-27" @default.
• W2034876825 title "Conversion of CuO Nanoplates into Porous Hybrid Cu₂O/Polypyrrole Nanoflakes through a Pyrrole-Induced Reductive Transformation Reaction" @default.
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• W2034876825 doi "https://doi.org/10.1002/asia.201300078" @default.
• W2034876825 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23610084" @default.
• W2034876825 hasPublicationYear "2013" @default.
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