Matches in SemOpenAlex for { <https://semopenalex.org/work/W2034878020> ?p ?o ?g. }
Showing items 1 to 97 of
97
with 100 items per page.
- W2034878020 endingPage "73" @default.
- W2034878020 startingPage "57" @default.
- W2034878020 abstract "PCILO semi-empirical quantum-chemical calculations have been conducted on 2-acetamido-2-deoxy-α-d-galactose (GaINAc) and the α-d-(1→3)-linked di-GaINAc disaccharide component of the Forssman antigen, in order to determine the favored orientations of their side groups, and the mutual orientations of the two pyranoid rings in the latter. For the N-acetyl group, three stable positions have been located, in one of which the plane of the amide unit is normal to the mean plane of the pyranoid ring. The orientation of the hydroxyl group attached to the anomeric carbon atom is found to be in accord with the exo-anomeric predictions. Furthermore, all of the side-group orientations of GaINAc found in the present study are in good agreement with the results of X-ray investigations. A grid-search method was used to locate all low-energy conformational regions for the glycosidic dihedral angles of O-(2-acetamido-2-deoxy-α-d-galactosyl)-(1→3)-2-acetamido-2-deoxy-d-galactose. Two allowed regions were found, and energy minimization was then performed in each of them. For this disaccharide, three sets of favored orientations of the (reducing) pyranose ring relative to the nonreducing ring were found. One set of glycosidic torsion angles is very close to that found from our X-ray diffraction results, n.m.r.-spectral observations, and hard-sphere exo-anomeric calculations." @default.
- W2034878020 created "2016-06-24" @default.
- W2034878020 creator A5007663085 @default.
- W2034878020 creator A5010613960 @default.
- W2034878020 date "1983-08-01" @default.
- W2034878020 modified "2023-09-27" @default.
- W2034878020 title "Pcilo calculations on 2-acetamido-2-deoxy-α-d-galactose and O-(2-acetamido-2-deoxy-α-d-galactosyl)-(1→3)-2-acetamido-2-deoxy-d-galactose" @default.
- W2034878020 cites W1564650229 @default.
- W2034878020 cites W1594603877 @default.
- W2034878020 cites W1939816201 @default.
- W2034878020 cites W1965645535 @default.
- W2034878020 cites W1967282310 @default.
- W2034878020 cites W1968835605 @default.
- W2034878020 cites W1975084378 @default.
- W2034878020 cites W1977297251 @default.
- W2034878020 cites W1993008824 @default.
- W2034878020 cites W1993945707 @default.
- W2034878020 cites W2007617715 @default.
- W2034878020 cites W2009828525 @default.
- W2034878020 cites W2012123997 @default.
- W2034878020 cites W2012919918 @default.
- W2034878020 cites W2014162473 @default.
- W2034878020 cites W2016628249 @default.
- W2034878020 cites W2018752537 @default.
- W2034878020 cites W2042352973 @default.
- W2034878020 cites W2051565074 @default.
- W2034878020 cites W2055980609 @default.
- W2034878020 cites W2063079197 @default.
- W2034878020 cites W2064699133 @default.
- W2034878020 cites W2072318954 @default.
- W2034878020 cites W2079589162 @default.
- W2034878020 cites W2085062291 @default.
- W2034878020 cites W2095100962 @default.
- W2034878020 cites W2335185195 @default.
- W2034878020 cites W2340232849 @default.
- W2034878020 cites W2996169403 @default.
- W2034878020 cites W3025623913 @default.
- W2034878020 doi "https://doi.org/10.1016/0008-6215(83)84045-2" @default.
- W2034878020 hasPublicationYear "1983" @default.
- W2034878020 type Work @default.
- W2034878020 sameAs 2034878020 @default.
- W2034878020 citedByCount "12" @default.
- W2034878020 crossrefType "journal-article" @default.
- W2034878020 hasAuthorship W2034878020A5007663085 @default.
- W2034878020 hasAuthorship W2034878020A5010613960 @default.
- W2034878020 hasConcept C112887158 @default.
- W2034878020 hasConcept C150487720 @default.
- W2034878020 hasConcept C178790620 @default.
- W2034878020 hasConcept C181199279 @default.
- W2034878020 hasConcept C185592680 @default.
- W2034878020 hasConcept C2777346074 @default.
- W2034878020 hasConcept C2778173381 @default.
- W2034878020 hasConcept C2778439535 @default.
- W2034878020 hasConcept C2780378348 @default.
- W2034878020 hasConcept C32909587 @default.
- W2034878020 hasConcept C34490408 @default.
- W2034878020 hasConcept C55493867 @default.
- W2034878020 hasConcept C71240020 @default.
- W2034878020 hasConcept C7947691 @default.
- W2034878020 hasConcept C8010536 @default.
- W2034878020 hasConcept C89025888 @default.
- W2034878020 hasConceptScore W2034878020C112887158 @default.
- W2034878020 hasConceptScore W2034878020C150487720 @default.
- W2034878020 hasConceptScore W2034878020C178790620 @default.
- W2034878020 hasConceptScore W2034878020C181199279 @default.
- W2034878020 hasConceptScore W2034878020C185592680 @default.
- W2034878020 hasConceptScore W2034878020C2777346074 @default.
- W2034878020 hasConceptScore W2034878020C2778173381 @default.
- W2034878020 hasConceptScore W2034878020C2778439535 @default.
- W2034878020 hasConceptScore W2034878020C2780378348 @default.
- W2034878020 hasConceptScore W2034878020C32909587 @default.
- W2034878020 hasConceptScore W2034878020C34490408 @default.
- W2034878020 hasConceptScore W2034878020C55493867 @default.
- W2034878020 hasConceptScore W2034878020C71240020 @default.
- W2034878020 hasConceptScore W2034878020C7947691 @default.
- W2034878020 hasConceptScore W2034878020C8010536 @default.
- W2034878020 hasConceptScore W2034878020C89025888 @default.
- W2034878020 hasLocation W20348780201 @default.
- W2034878020 hasOpenAccess W2034878020 @default.
- W2034878020 hasPrimaryLocation W20348780201 @default.
- W2034878020 hasRelatedWork W1935641526 @default.
- W2034878020 hasRelatedWork W1964307003 @default.
- W2034878020 hasRelatedWork W1982251037 @default.
- W2034878020 hasRelatedWork W1994722760 @default.
- W2034878020 hasRelatedWork W2000504553 @default.
- W2034878020 hasRelatedWork W2000900553 @default.
- W2034878020 hasRelatedWork W2031537740 @default.
- W2034878020 hasRelatedWork W2067338469 @default.
- W2034878020 hasRelatedWork W2089397046 @default.
- W2034878020 hasRelatedWork W3217417743 @default.
- W2034878020 hasVolume "119" @default.
- W2034878020 isParatext "false" @default.
- W2034878020 isRetracted "false" @default.
- W2034878020 magId "2034878020" @default.
- W2034878020 workType "article" @default.