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- W2034879952 abstract "Abstract The condensation reaction between ethyl cyano‐pyruvate and a 2‐methylmercapto‐benzothiazole quaternary salt yields the corresponding 2‐cyano‐methylene base. This product is identical with the compound which is obtained when the same quaternary salt is allowed to react with cyano‐acetic acid, or when one molecule of an acid (HX), is eliminated from a quaternary salt of 2‐benzothiazolylacetonitrile. The analogous 2‐carbethoxy‐methylene base is obtained by the reaction of a 2‐methylmercapto‐benzothiazole quaternary salt with ethyl carbethoxypyruvate or with ethyl acetone‐dicarboxylate. The same base can also be obtained by the elimination of HX from a quaternary salt of ethyl 2‐benzothiazolyl acetate, or by performing a soft hydrolysis reaction on the corresponding 2‐(acetyl‐carbethoxy)‐methylene base." @default.
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- W2034879952 date "1950-01-01" @default.
- W2034879952 modified "2023-09-23" @default.
- W2034879952 title "Dérivés méthyléniques de bases hétérocycliques" @default.
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- W2034879952 doi "https://doi.org/10.1002/bscb.19500590903" @default.
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