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- W2034884400 abstract "The conversion of myo-inositol to epi-inositol can be achieved by the hydride reduction of an intermediate epi-inosose derived from myo-inositol. (−)-epi-Inosose, (I), crystallized in the monoclinic space group P21, with two independent molecules in the asymmetric unit [Hosomi et al. (2000). Acta Cryst. C56, e584–e585]. On the other hand, (2RS,3SR,5SR,6SR)-epi-inosose, C6H10O6, (II), crystallized in the orthorhombic space group Pca21. Interestingly, the conformation of the molecules in the two structures is nearly the same, the only difference being the orientation of the C-3 and C-4 hydroxy H atoms. As a result, the molecular organization achieved mainly through strong O—H⋯O hydrogen bonding in the racemic and homochiral lattices is similar. The compound also follows Wallach's rule, in that the racemic crystals are denser than the optically active form." @default.
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- W2034884400 date "2011-10-06" @default.
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- W2034884400 title "Comparison of racemic<i>epi</i>-inosose and (−)-<i>epi</i>-inosose" @default.
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- W2034884400 doi "https://doi.org/10.1107/s0108270111039412" @default.
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