Matches in SemOpenAlex for { <https://semopenalex.org/work/W2034885368> ?p ?o ?g. }
Showing items 1 to 96 of
96
with 100 items per page.
- W2034885368 endingPage "128" @default.
- W2034885368 startingPage "122" @default.
- W2034885368 abstract "The present study reports the development, validation and application of a new green liquid chromatographic method for the determination of glutathione (GSH) in vegetable samples. In this work we introduce—for the first time—ethyl propiolate (EP) as an advantageous post-column derivatization reagent for thiolic compounds. GSH (tR = 6.60 min) and N-acetylcysteine (NAC, internal standard) (tR = 11.80 min) were separated efficiently from matrix endogenous compounds by using a 100% aqueous mobile phase (0.1%, v/v CH3COOH in 1 mmol L−1 EDTA, QV = 0.5 mL min−1) and a Prevail® reversed phase column that offers the advantage of stable packing material in aqueous mobile phases. The parameters of the post-column reaction (pH, amount concentration of the reagent, flow rates, length of the reaction coil and temperature) were studied. The linear determination range for GSH was 1–200 μmol L−1 and the LOD was 0.1 μmol L−1 (S/N = 3). Total endogenous GSH was determined in broccoli, potato, asparagus and Brussels sprouts using the standards addition approach. The accuracy was evaluated by both recovery experiments (R = 91–110%) and comparison to an o-phthalaldehyde/glycine corroborative post-column derivatization fluorimetric method." @default.
- W2034885368 created "2016-06-24" @default.
- W2034885368 creator A5026964210 @default.
- W2034885368 creator A5055929840 @default.
- W2034885368 creator A5064903411 @default.
- W2034885368 date "2011-03-01" @default.
- W2034885368 modified "2023-10-16" @default.
- W2034885368 title "Ethyl propiolate as a post-column derivatization reagent for thiols: Development of a green liquid chromatographic method for the determination of glutathione in vegetables" @default.
- W2034885368 cites W1891967301 @default.
- W2034885368 cites W1966902263 @default.
- W2034885368 cites W1974952941 @default.
- W2034885368 cites W1978860511 @default.
- W2034885368 cites W1994182633 @default.
- W2034885368 cites W1997527498 @default.
- W2034885368 cites W2008557491 @default.
- W2034885368 cites W2014957067 @default.
- W2034885368 cites W2022225843 @default.
- W2034885368 cites W2026328370 @default.
- W2034885368 cites W2026761906 @default.
- W2034885368 cites W2027299621 @default.
- W2034885368 cites W2032137598 @default.
- W2034885368 cites W2037365087 @default.
- W2034885368 cites W2042549443 @default.
- W2034885368 cites W2057521823 @default.
- W2034885368 cites W2058864285 @default.
- W2034885368 cites W2062669701 @default.
- W2034885368 cites W2065906579 @default.
- W2034885368 cites W2067743492 @default.
- W2034885368 cites W2075441803 @default.
- W2034885368 cites W2075796234 @default.
- W2034885368 cites W2085731144 @default.
- W2034885368 cites W2089360722 @default.
- W2034885368 cites W2130004951 @default.
- W2034885368 cites W64264534 @default.
- W2034885368 doi "https://doi.org/10.1016/j.aca.2011.02.003" @default.
- W2034885368 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21414445" @default.
- W2034885368 hasPublicationYear "2011" @default.
- W2034885368 type Work @default.
- W2034885368 sameAs 2034885368 @default.
- W2034885368 citedByCount "29" @default.
- W2034885368 countsByYear W20348853682012 @default.
- W2034885368 countsByYear W20348853682013 @default.
- W2034885368 countsByYear W20348853682014 @default.
- W2034885368 countsByYear W20348853682015 @default.
- W2034885368 countsByYear W20348853682016 @default.
- W2034885368 countsByYear W20348853682017 @default.
- W2034885368 countsByYear W20348853682018 @default.
- W2034885368 countsByYear W20348853682020 @default.
- W2034885368 countsByYear W20348853682021 @default.
- W2034885368 countsByYear W20348853682023 @default.
- W2034885368 crossrefType "journal-article" @default.
- W2034885368 hasAuthorship W2034885368A5026964210 @default.
- W2034885368 hasAuthorship W2034885368A5055929840 @default.
- W2034885368 hasAuthorship W2034885368A5064903411 @default.
- W2034885368 hasConcept C106487976 @default.
- W2034885368 hasConcept C178790620 @default.
- W2034885368 hasConcept C179998833 @default.
- W2034885368 hasConcept C181199279 @default.
- W2034885368 hasConcept C184651966 @default.
- W2034885368 hasConcept C185592680 @default.
- W2034885368 hasConcept C2776923573 @default.
- W2034885368 hasConcept C40875361 @default.
- W2034885368 hasConcept C43617362 @default.
- W2034885368 hasConcept C538909803 @default.
- W2034885368 hasConceptScore W2034885368C106487976 @default.
- W2034885368 hasConceptScore W2034885368C178790620 @default.
- W2034885368 hasConceptScore W2034885368C179998833 @default.
- W2034885368 hasConceptScore W2034885368C181199279 @default.
- W2034885368 hasConceptScore W2034885368C184651966 @default.
- W2034885368 hasConceptScore W2034885368C185592680 @default.
- W2034885368 hasConceptScore W2034885368C2776923573 @default.
- W2034885368 hasConceptScore W2034885368C40875361 @default.
- W2034885368 hasConceptScore W2034885368C43617362 @default.
- W2034885368 hasConceptScore W2034885368C538909803 @default.
- W2034885368 hasIssue "1" @default.
- W2034885368 hasLocation W20348853681 @default.
- W2034885368 hasLocation W20348853682 @default.
- W2034885368 hasOpenAccess W2034885368 @default.
- W2034885368 hasPrimaryLocation W20348853681 @default.
- W2034885368 hasRelatedWork W1485351367 @default.
- W2034885368 hasRelatedWork W1966223683 @default.
- W2034885368 hasRelatedWork W1966246554 @default.
- W2034885368 hasRelatedWork W1993734318 @default.
- W2034885368 hasRelatedWork W2068686024 @default.
- W2034885368 hasRelatedWork W2368050516 @default.
- W2034885368 hasRelatedWork W2375148030 @default.
- W2034885368 hasRelatedWork W2385928967 @default.
- W2034885368 hasRelatedWork W2797791170 @default.
- W2034885368 hasRelatedWork W3112916271 @default.
- W2034885368 hasVolume "690" @default.
- W2034885368 isParatext "false" @default.
- W2034885368 isRetracted "false" @default.
- W2034885368 magId "2034885368" @default.
- W2034885368 workType "article" @default.