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- W2034885908 abstract "We have recently developed a new method for synthesizing polyrotaxanes with a high covering ratio, rigidity, photoluminescence efficiency, and solubility in a variety of organic solvents through the polymerization of structurally defined rotaxane monomers. The rigid rodlike structure of the π-conjugated core polymers in these polyrotaxanes is thought to facilitate the effective transport of charge carriers. Here we applied this method to the synthesis of a polyrotaxane having a poly(phenylene ethynylene) backbone by the Sonogashira copolymerization of a structurally defined rotaxane with a linker molecule. According to time-resolved microwave conductivity and transient absorption spectroscopy measurements, the hole mobility along the π-conjugated polymer chain of the polyrotaxane thus formed was extremely high and comparable to that in amorphous silicon." @default.
- W2034885908 created "2016-06-24" @default.
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- W2034885908 date "2009-11-24" @default.
- W2034885908 modified "2023-10-07" @default.
- W2034885908 title "Insulated Molecular Wire with Highly Conductive π-Conjugated Polymer Core" @default.
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- W2034885908 doi "https://doi.org/10.1021/ja908783f" @default.
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