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- W2034887594 abstract "The In–Ir phase diagram was investigated by means of X-ray diffraction, electron probe microanalysis and thermal analysis. The existence of the two intermetallic compounds In3Ir and In2Ir was confirmed, and it was found, that In3Ir transforms into a low-temperature modification In3Ir-LT (CFe3-type structure, oP16, Pnma) at temperatures below about 350 °C. The peritectic decomposition reaction of In3Ir and In2Ir at 981 °C and 1188 °C, resp., was confirmed. There are no indications of a liquid miscibility gap as suggested earlier in the literature. On the other hand, some of the experimental results point to the existence of a metastable high-temperature phase In54Ir46. Enthalpies of mixing were determined by high-temperature drop-calorimetry between 1190 and 1390 °C. The minimum in the extrapolated enthalpy of mixing curve is about −18 kJ mol−1 at a composition slightly above xIr=0.5." @default.
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- W2034887594 date "2002-10-01" @default.
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- W2034887594 title "The binary system In–Ir: a new investigation of phase relationships, crystal structures, and enthalpies of mixing" @default.
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- W2034887594 doi "https://doi.org/10.1016/s0925-8388(02)00287-6" @default.
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