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• W2034887752 abstract "In ionic crystals of the form M(+)X(-), certain covalently bonded anion groups X(-) are particularly associated with instability. The heavier metal cations M(+) enhance this. Very sensitive explosives occur within the extended azide family, where X(-) = CNO(-), N(3)(-), NCO(-), or NCS(-) (an isoelectronic set of unsaturated linear triatomic anions). Another such family are the globular oxyanions X(-) = ClO(2)(-), ClO(3)(-), ClO(4)(-), NO(3)(-), and MnO(4)(-). Mishandling of NH(4)NO(3) or NH(4)ClO(4) has caused major disasters. An irreversible cyclic mechanism is proposed for such decomposition, involving mechanoelectronic band-gap excitation and coalescence of X with X(-). From an intracrystalline ion-molecule collision complex, the singly charged dianion X(2)(-), exothermic reactions proceed with high yield." @default.
• W2034887752 created "2016-06-24" @default.
• W2034887752 creator A5077222250 @default.
• W2034887752 date "1989-07-07" @default.
• W2034887752 modified "2023-09-27" @default.
• W2034887752 title "Explosive Molecular Ionic Crystals" @default.
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• W2034887752 doi "https://doi.org/10.1126/science.245.4913.37" @default.
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