FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2034889166> ?p ?o ?g. }

• W2034889166 endingPage "9797" @default.
• W2034889166 startingPage "9789" @default.
• W2034889166 abstract "A one-pot C2-amidoglycosylation reaction for the synthesis of 2-N-acyl-2-deoxy-beta-pyranosides from glycals is described. Glycal donors activated by the reagent combination of thianthrene-5-oxide (11) and Tf2O, followed by treatment with an amide nucleophile and a glycosyl acceptor, lead to the formation of various C2-amidoglycoconjugates. Both the C2-nitrogen transfer and the glycosidic bond formation proceed stereoselectively, allowing for the introduction of both natural and nonnatural amide functionalities at C2 with concomitant anomeric bond formation in a one-pot procedure. Tracking of the reaction by low-temperature NMR spectroscopy employing 15N- and 18O-isotope labels suggests a mechanism involving the formation of the C2-sulfonium glycosyl imidate 39 as well as oxazoline 37 as key intermediates in this novel oxidative glycosylation process." @default.
• W2034889166 created "2016-06-24" @default.
• W2034889166 creator A5035282947 @default.
• W2034889166 creator A5064147142 @default.
• W2034889166 date "2002-07-27" @default.
• W2034889166 modified "2023-10-09" @default.
• W2034889166 title "<i>C2</i>-Amidoglycosylation. Scope and Mechanism of Nitrogen Transfer" @default.
• W2034889166 cites W1964316590 @default.
• W2034889166 cites W1967750525 @default.
• W2034889166 cites W1971212455 @default.
• W2034889166 cites W1987221550 @default.
• W2034889166 cites W1994051597 @default.
• W2034889166 cites W2020604044 @default.
• W2034889166 cites W2028062152 @default.
• W2034889166 cites W2032714303 @default.
• W2034889166 cites W2041305088 @default.
• W2034889166 cites W2049803921 @default.
• W2034889166 cites W2056927024 @default.
• W2034889166 cites W2057456110 @default.
• W2034889166 cites W2058489747 @default.
• W2034889166 cites W2061639446 @default.
• W2034889166 cites W2061880080 @default.
• W2034889166 cites W2063573955 @default.
• W2034889166 cites W2069913189 @default.
• W2034889166 cites W2070625978 @default.
• W2034889166 cites W2080116571 @default.
• W2034889166 cites W2089886461 @default.
• W2034889166 cites W2090804693 @default.
• W2034889166 cites W2103598870 @default.
• W2034889166 cites W2105765586 @default.
• W2034889166 cites W2138899864 @default.
• W2034889166 cites W2145639501 @default.
• W2034889166 cites W2147901765 @default.
• W2034889166 cites W2160045029 @default.
• W2034889166 cites W2172087043 @default.
• W2034889166 cites W2337467320 @default.
• W2034889166 cites W2949212949 @default.
• W2034889166 cites W2949301374 @default.
• W2034889166 cites W2949358521 @default.
• W2034889166 cites W2951361956 @default.
• W2034889166 cites W2951663575 @default.
• W2034889166 cites W2951712111 @default.
• W2034889166 cites W3004820402 @default.
• W2034889166 cites W4251775387 @default.
• W2034889166 doi "https://doi.org/10.1021/ja026281n" @default.
• W2034889166 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/12175238" @default.
• W2034889166 hasPublicationYear "2002" @default.
• W2034889166 type Work @default.
• W2034889166 sameAs 2034889166 @default.
• W2034889166 citedByCount "82" @default.
• W2034889166 countsByYear W20348891662012 @default.
• W2034889166 countsByYear W20348891662013 @default.
• W2034889166 countsByYear W20348891662014 @default.
• W2034889166 countsByYear W20348891662015 @default.
• W2034889166 countsByYear W20348891662016 @default.
• W2034889166 countsByYear W20348891662017 @default.
• W2034889166 countsByYear W20348891662018 @default.
• W2034889166 countsByYear W20348891662019 @default.
• W2034889166 countsByYear W20348891662021 @default.
• W2034889166 countsByYear W20348891662022 @default.
• W2034889166 countsByYear W20348891662023 @default.
• W2034889166 crossrefType "journal-article" @default.
• W2034889166 hasAuthorship W2034889166A5035282947 @default.
• W2034889166 hasAuthorship W2034889166A5064147142 @default.
• W2034889166 hasConcept C150487720 @default.
• W2034889166 hasConcept C161790260 @default.
• W2034889166 hasConcept C178790620 @default.
• W2034889166 hasConcept C178907741 @default.
• W2034889166 hasConcept C181199279 @default.
• W2034889166 hasConcept C181647583 @default.
• W2034889166 hasConcept C185592680 @default.
• W2034889166 hasConcept C21951064 @default.
• W2034889166 hasConcept C2775944816 @default.
• W2034889166 hasConcept C2776371256 @default.
• W2034889166 hasConcept C2777040163 @default.
• W2034889166 hasConcept C2777313579 @default.
• W2034889166 hasConcept C2778439535 @default.
• W2034889166 hasConcept C2780906977 @default.
• W2034889166 hasConcept C2781259705 @default.
• W2034889166 hasConcept C55493867 @default.
• W2034889166 hasConcept C71240020 @default.
• W2034889166 hasConcept C7947691 @default.
• W2034889166 hasConceptScore W2034889166C150487720 @default.
• W2034889166 hasConceptScore W2034889166C161790260 @default.
• W2034889166 hasConceptScore W2034889166C178790620 @default.
• W2034889166 hasConceptScore W2034889166C178907741 @default.
• W2034889166 hasConceptScore W2034889166C181199279 @default.
• W2034889166 hasConceptScore W2034889166C181647583 @default.
• W2034889166 hasConceptScore W2034889166C185592680 @default.
• W2034889166 hasConceptScore W2034889166C21951064 @default.
• W2034889166 hasConceptScore W2034889166C2775944816 @default.
• W2034889166 hasConceptScore W2034889166C2776371256 @default.
• W2034889166 hasConceptScore W2034889166C2777040163 @default.
• W2034889166 hasConceptScore W2034889166C2777313579 @default.
• W2034889166 hasConceptScore W2034889166C2778439535 @default.
• W2034889166 hasConceptScore W2034889166C2780906977 @default.
• W2034889166 hasConceptScore W2034889166C2781259705 @default.
• W2034889166 hasConceptScore W2034889166C55493867 @default.

• next