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• W2034889178 abstract "The complexes: [Co(BAE)(PEt3)]ClO4 · H2O(BAE=bis(acetylacetone)ethylenediimine) and [Co(BBE)(PR3)]ClO4 · H2O, (BBE=bis(benzoylacetone)ethylenediimine and R=Et, Bu), were synthesized and characterized. The equilibrium constants and the thermodynamic parameters were measured spectrophotometrically for 1∶1 adduct formation of [Co(chel)L]ClO4 · H2O, (where chel=BAE, BBE and L=PBu3, PEt3 and PMe2Ph) as acceptors and P(OR)3 (R=Me, Et and Ipr) as donors, in acetonitrile in constant ionic strength (I=0.01M Et4NClO4) and at various temperatures T=293 to 313 K. The trend of the equilibrium constants of five coordinate cobalt(III) Schiff base complexes toward a given phosphite donor according to the axial ligand is as follows: PMe2Ph>PBu3≈PEt3. Also, the trend of the equilibrium constants of the donors (phosphite) toward a given cobalt(III) Schiff base complex is as follows: P(OEt)3>P(OIpr)3>P(OMe)3. The trend of the equilibrium constants of cobalt(III) Schiff base complexes with respect to the Schiff bases used in this research is as follows: BBE>BAE." @default.
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• W2034889178 date "2005-09-01" @default.
• W2034889178 modified "2023-10-16" @default.
• W2034889178 title "Synthesis and Thermodynamic Studies of Cobalt(III) Schiff Base Complexes" @default.
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• W2034889178 doi "https://doi.org/10.1080/15533170500225441" @default.
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