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- W2034889871 abstract "Two novel coordination polymers, [Cd(BIM)Cl2]n (1) and [Pb(BIM)Cl2]n (2) [wherein BIM = bis(imidazol-1-yl)methane], were synthesized by the reactions of the BIM ligand with CdCl2 and PbCl2, respectively. They were characterized by elemental analyses, IR, TGA and X-ray single-crystal diffraction techniques. Single-crystal X-ray structure analyses showed there is a pseudooctahedral arrangement around the cadmium atom in the complex 1. It has a three-dimensional network which contains one-dimensional inorganic-organic hybrid chains and μ2-bridging chloride ligands. A rare pentacoordinate square-pyramidal arrangement was adopted for the lead(II) atom in the complex 2, which has an unusual two-dimensional layer structure of macrometallacycles crosslinked with the bridging Pb2Cl2 units. The metal atoms in both complexes were coordinated with two BIM ligands in cis arrangement and bridged by μ2-bridging chloride ligands." @default.
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- W2034889871 date "2009-06-08" @default.
- W2034889871 modified "2023-10-16" @default.
- W2034889871 title "Syntheses and Crystal Structures of Two Chloro-Bridged Coordination Polymers [Cd(BIM)Cl2]nand [Pb(BIM)Cl2]n" @default.
- W2034889871 doi "https://doi.org/10.1002/zaac.200900092" @default.
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