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- W2034894030 abstract "The applicability of the persistent chain model to describe the way in which the dimensions of flexible (persistent chain length, a, approximately 10 å) and rigid (a⩾100 Å) chains depend on molecular weight is considered. It is shown that the model gives a rigorous description for rigid chains. Expressions are derived that connect the persistent length of the rigid chain with the range of the local vibrations of the links and with the unperturbed helical structure of the chain. A discussion is given of the chain flexibility of polybutylisocyanate, the α-helix of polypeptides and the double helix of DNA. It is shown that variations in the angles of internal rotation in the range 5–10° are sufficient to account for the observed flexibility." @default.
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- W2034894030 date "1974-11-01" @default.
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- W2034894030 title "Dimensions of semi-rigid macromolecules and the fluctuation mechanism of flexibility" @default.
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- W2034894030 doi "https://doi.org/10.1016/0032-3950(74)90117-8" @default.
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