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- W2034896263 abstract "The tetra-imino ferrocenophane (1) was cocrystallized with 1,4-diiodo-tetrafluoro-benzene (TFDIB). In the resulting compound 2, two of the four ferrocenophane nitrogens show interactions with the iodine atoms of TFDIB leading to a polymeric structure with extended linear alternating electron donor (1) and acceptor (TFDIB) molecule chains. For the first time, imino nitrogens are involved in this type of halogen bonding. The N⋯I non-covalent bonds (N⋯I distances 2.879(5) and 2.896(5) Å; N⋯I–C angles 171.1(2) and 178.1(2)°) are the directing interactions responsible for the observed self-assembly. The ferrocene fragments of the macrocycle are in an almost perpendicular conformation. Mössbauer spectroscopy indicates the sole presence of low spin iron (II). The temperature dependence of the magnetic susceptibility is corresponding to a quasi-diamagnetic compound." @default.
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- W2034896263 date "2004-03-01" @default.
- W2034896263 modified "2023-10-18" @default.
- W2034896263 title "Self-assembly via (N⋯I) non-covalent bonds between 1,4-diiodo-tetrafluoro-benzene and a tetra-imino ferrocenophane" @default.
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- W2034896263 doi "https://doi.org/10.1016/j.molstruc.2003.11.031" @default.
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