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- W2034897734 abstract "Homologues of the orthorhombic form of Mo4O11, belonging to the series Mm+2O3m+4, have been prepared in the Mo-W-O system and structurally characterized by X-ray powder diffraction and electron microscopy. The structures are built up of corner-sharing MO6 octahedra in ReO3-type slabs of characteristic width m and alternatingly mirrored orientation, connected by MO4 tetrahedra along planes where pentagonal tunnels are formed. The structures can be designated by [m, m̄ ]. The phases (Mo,W)4O11, (=[6,6̄]), and (Mo,W)9O25 (=[7,7̄]) were obtained almost pure and slabs of other widths, intergrown in more or less disordered fashion, were frequently observed by HREM. Slabs in parallel orientation, as in Mo4O11(mon), have also been seen, as well as a coherent boundary across which the structure [6,6̄] changes into ∼[5,7̄]." @default.
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- W2034897734 date "1994-07-01" @default.
- W2034897734 modified "2023-09-26" @default.
- W2034897734 title "Ordered and Disordered Homologues of Orthorhombic Mo4O11 in the Mo-W-O System" @default.
- W2034897734 doi "https://doi.org/10.1006/jssc.1994.1205" @default.
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