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- W2034899081 abstract "Condensation of 2-amino esters with carbonyl compounds leads to simple generation of ester-stabilized azomethine ylides which are trapped by olefinic dipolarophiles as cycloadducts. Anti ylides are exclusively involved in the cycloadditions when N-substituted 2-amino esters are employed for the ylide generation, while syn ylides from N-unsubstituted 2-amino esters. Relative stability among all possible ylide isomers has been inspected and the selective involvement of particular ylidic forms has been explained on the ground of 1,5-dipole interaction or hydrogen bonding stabilization. Endo- and exo-selectivity of the cycloadditions is also discussed." @default.
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- W2034899081 date "1987-11-01" @default.
- W2034899081 modified "2023-10-13" @default.
- W2034899081 title "Simple Generation of Ester-Stabilized Azomethine Ylides from 2-Amino Esters and Carbonyl Compounds. Stereochemistry of Their Cycloadditions" @default.
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- W2034899081 doi "https://doi.org/10.1246/bcsj.60.4067" @default.
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