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- W2034926066 abstract "An automated very high temperature calorimeter has been used to investigate the partial and integral enthalpies of mixing of liquid nickel+tin alloys in the temperature and molar fraction range 867<T/K<1579 and 0<xNt<0.80 respectively. The enthalpies of mixing, ΔmaxH°80 = f(xNt) are exothermic over the entire concentration range. They are represented by the following equation for temperatures between 1530 and 1580 K: ΔmaxH°10/kJ mol 1 = x(1−x)(−46.01−6.788x−209.616x2+203.879x3−20.145x4) where x = xNt. The coordinates of the minimum are ΔmikJ° m = −20.2±0.6 kJ mol−1 at xNt = 0.60. The limiting partial molar enthalpy of Ni in liquid tin, referred to liquid Ni, was determined to be h°m (Ni(t) in ∞ Sn(t))/kJ mol 1 = −36.48−12960/T over the entire temperature range scanned. The change in Fermi enthalpy on alloying indicates a restricted number of electrons transferred from Sn to Ni for alloys with xSn>0.75. Higher tin concentrations do not change the number of electrons accepted by Ni." @default.
- W2034926066 created "2016-06-24" @default.
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- W2034926066 date "1997-01-01" @default.
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- W2034926066 title "Thermodynamics of nickel-tin liquid alloys" @default.
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- W2034926066 doi "https://doi.org/10.1016/s0925-8388(96)02594-7" @default.
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