FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2034931427> ?p ?o ?g. }

• W2034931427 endingPage "39" @default.
• W2034931427 startingPage "31" @default.
• W2034931427 abstract "K-edge X-ray absorption spectroscopy (XAS) is a subtle probe of the chemical environment and oxidation state of the elements. Thus, the change in the energy position of the rising K-edge inflection in the XAS spectrum of [V(H2O)6]3+ in pH 0, 1, 2 and 3 aqueous solutions produces a titration curve that can be fit (r=0.999) with an unusual model involving two cooperative deprotonations, yielding pKa1=1.5±0.1 and pKa2=1.1±0.1. These pH effects on VIII K-edge XAS spectra vary with the medium (40% aqueous methanol) and the counterion (Cl−, SO42−). Applied to whole blood of the tunicate Ascidia ceratodes, as collected from Monterey Bay, California, fits to the vanadium K-edge XAS spectra produced a detailed speciation of the major endogenous cellular VIII (complex, percent): [V(H2O)6]3+, 23.6%; [V(SO4)(H2O)5]+, 38.1%; [V(SO4)2(H2O)4]−, 19.8%, and; [V(SO4)(OH)2(H2O)3], 7.7%. Genus-associated differences in the distribution of blood cell vanadium appear on comparison with a sample of whole blood from Phallusia nigra, in which most of the vanadium is distributed among [V(H2O)6]3+, 34%; tris-chelated VIII, 33%, and; [VIVO(H2O)5]2+, 30%, with no VIII complex ions at all detected. Vanadium distribution in the blood cells of a single specimen of A. ceratodes from Bodega Bay, California is shown to vary significantly from the norm of animals collected from Monterey Bay, California. Finally, preliminary results are reported from in vitro experiments exposing A. ceratodes blood cells to vanadyl ion, showing active uptake and incorporation." @default.
• W2034931427 created "2016-06-24" @default.
• W2034931427 creator A5044648395 @default.
• W2034931427 date "2003-02-01" @default.
• W2034931427 modified "2023-10-10" @default.
• W2034931427 title "Medium-dependence of vanadium K-edge X-ray absorption spectra with application to blood cells from phlebobranch tunicates" @default.
• W2034931427 cites W1516461961 @default.
• W2034931427 cites W1550642408 @default.
• W2034931427 cites W1972146900 @default.
• W2034931427 cites W1973499914 @default.
• W2034931427 cites W1979031178 @default.
• W2034931427 cites W1979534237 @default.
• W2034931427 cites W1982204940 @default.
• W2034931427 cites W1988701085 @default.
• W2034931427 cites W1989570535 @default.
• W2034931427 cites W1995872020 @default.
• W2034931427 cites W2003069849 @default.
• W2034931427 cites W2006416695 @default.
• W2034931427 cites W2017525982 @default.
• W2034931427 cites W2020905474 @default.
• W2034931427 cites W2020914147 @default.
• W2034931427 cites W2028129650 @default.
• W2034931427 cites W2029536094 @default.
• W2034931427 cites W2033531958 @default.
• W2034931427 cites W2040336879 @default.
• W2034931427 cites W2042551322 @default.
• W2034931427 cites W2045216152 @default.
• W2034931427 cites W2050452392 @default.
• W2034931427 cites W2051374275 @default.
• W2034931427 cites W2057272760 @default.
• W2034931427 cites W2061576548 @default.
• W2034931427 cites W2068974564 @default.
• W2034931427 cites W2071961454 @default.
• W2034931427 cites W2075878703 @default.
• W2034931427 cites W2077910335 @default.
• W2034931427 cites W2078171437 @default.
• W2034931427 cites W2084950334 @default.
• W2034931427 cites W2113577283 @default.
• W2034931427 cites W2341283081 @default.
• W2034931427 cites W2798482831 @default.
• W2034931427 cites W303516556 @default.
• W2034931427 doi "https://doi.org/10.1016/s0010-8545(02)00224-2" @default.
• W2034931427 hasPublicationYear "2003" @default.
• W2034931427 type Work @default.
• W2034931427 sameAs 2034931427 @default.
• W2034931427 citedByCount "41" @default.
• W2034931427 countsByYear W20349314272012 @default.
• W2034931427 countsByYear W20349314272013 @default.
• W2034931427 countsByYear W20349314272014 @default.
• W2034931427 countsByYear W20349314272015 @default.
• W2034931427 countsByYear W20349314272016 @default.
• W2034931427 countsByYear W20349314272017 @default.
• W2034931427 countsByYear W20349314272018 @default.
• W2034931427 countsByYear W20349314272020 @default.
• W2034931427 countsByYear W20349314272021 @default.
• W2034931427 crossrefType "journal-article" @default.
• W2034931427 hasAuthorship W2034931427A5044648395 @default.
• W2034931427 hasConcept C113196181 @default.
• W2034931427 hasConcept C119824511 @default.
• W2034931427 hasConcept C121332964 @default.
• W2034931427 hasConcept C147789679 @default.
• W2034931427 hasConcept C178790620 @default.
• W2034931427 hasConcept C179104552 @default.
• W2034931427 hasConcept C184651966 @default.
• W2034931427 hasConcept C184866935 @default.
• W2034931427 hasConcept C185592680 @default.
• W2034931427 hasConcept C2778591166 @default.
• W2034931427 hasConcept C2780852000 @default.
• W2034931427 hasConcept C43617362 @default.
• W2034931427 hasConcept C504678139 @default.
• W2034931427 hasConcept C544153396 @default.
• W2034931427 hasConcept C59244509 @default.
• W2034931427 hasConcept C62284982 @default.
• W2034931427 hasConcept C62520636 @default.
• W2034931427 hasConcept C8010536 @default.
• W2034931427 hasConceptScore W2034931427C113196181 @default.
• W2034931427 hasConceptScore W2034931427C119824511 @default.
• W2034931427 hasConceptScore W2034931427C121332964 @default.
• W2034931427 hasConceptScore W2034931427C147789679 @default.
• W2034931427 hasConceptScore W2034931427C178790620 @default.
• W2034931427 hasConceptScore W2034931427C179104552 @default.
• W2034931427 hasConceptScore W2034931427C184651966 @default.
• W2034931427 hasConceptScore W2034931427C184866935 @default.
• W2034931427 hasConceptScore W2034931427C185592680 @default.
• W2034931427 hasConceptScore W2034931427C2778591166 @default.
• W2034931427 hasConceptScore W2034931427C2780852000 @default.
• W2034931427 hasConceptScore W2034931427C43617362 @default.
• W2034931427 hasConceptScore W2034931427C504678139 @default.
• W2034931427 hasConceptScore W2034931427C544153396 @default.
• W2034931427 hasConceptScore W2034931427C59244509 @default.
• W2034931427 hasConceptScore W2034931427C62284982 @default.
• W2034931427 hasConceptScore W2034931427C62520636 @default.
• W2034931427 hasConceptScore W2034931427C8010536 @default.
• W2034931427 hasIssue "1-2" @default.
• W2034931427 hasLocation W20349314271 @default.
• W2034931427 hasOpenAccess W2034931427 @default.
• W2034931427 hasPrimaryLocation W20349314271 @default.
• W2034931427 hasRelatedWork W1836923993 @default.

• next