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• W2034950254 endingPage "6578" @default.
• W2034950254 startingPage "6578" @default.
• W2034950254 abstract "Cyclopalladated azido dimers having various C,N-donor ligands, [Pd(μ-N3)(C,N-Ln)]2 (L1H = 2-(2′-thienyl)pyridine; L2H = azobenzene; L3H = 3,3′-dimethylazobenzene; L4H = N,N′-dimethylbenzylamine; L5H = 2-phenylpyridine), underwent cleavage with tertiary (or chelating) phosphines to form the cyclopalladated [Pd(N3)(PR3)(C,N-L)], the σ-bonded [Pd(N3)(PR3)2(C-L)], or the dinuclear-cyclopalladated [PdN3(PR3)(C,N-L)]2(μ-P∼P) complexes. In particular, treating [Pd(μ-N3)(C,N-L)]2 with the basic chelating phosphine (depe or dmpe) produced the homoleptic bis(chelating) complex [Pd(C,N-Ln)2] (n = 1–3). Complex [Pd(N3)(PR3)(C,N-L4)] or [Pd(N3)(PR3)2(C-L4)] reacted with aryl isocyanides to selectively give the imidoyl [Pd(N3)(–CN–Ar)(PR3)(N-L4)] or the imidoyl carbodiimido complex [Pd(NCN–Ar)(–CN–Ar)(PR3)(N-L4)], which was formed by the CN–Ar insertion into the orthometallated Pd–C bond on the phenyl moiety or the interaction into the Pd–N3 bond of the supporting ligand. In addition, reactions of [Pd(N3)(PR3)2(C-Ln)] (n = 1, 2, 4) with R–NCS {R = i-Pr, C6H4–NCS, (CH3)3Si} gave the S-coordinated tetrazole–thiolato Pd(II) complexes. Finally, the catalytic activity of the cyclopalladated azido complexes was evaluated." @default.
• W2034950254 created "2016-06-24" @default.
• W2034950254 creator A5013018378 @default.
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• W2034950254 creator A5065385226 @default.
• W2034950254 creator A5088452990 @default.
• W2034950254 date "2009-01-01" @default.
• W2034950254 modified "2023-10-18" @default.
• W2034950254 title "Cyclopalladated azido complexes containing C,N-donor (HC∼N = 2-(2′-thienyl)pyridine, azobenzene, 3,3′-dimethyl azobenzene, N,N′-dimethylbenzylamine, 2-phenylpyridine) ligands: reactivity towards organic unsaturated compounds and catalytic properties" @default.
• W2034950254 cites W1581716159 @default.
• W2034950254 cites W1965042700 @default.
• W2034950254 cites W1968109788 @default.
• W2034950254 cites W1969471627 @default.
• W2034950254 cites W1969822178 @default.
• W2034950254 cites W1969867519 @default.
• W2034950254 cites W1970486780 @default.
• W2034950254 cites W1970530829 @default.
• W2034950254 cites W1976199737 @default.
• W2034950254 cites W1977918603 @default.
• W2034950254 cites W1978890358 @default.
• W2034950254 cites W1982296964 @default.
• W2034950254 cites W1982440680 @default.
• W2034950254 cites W1985286229 @default.
• W2034950254 cites W1994215637 @default.
• W2034950254 cites W1994813579 @default.
• W2034950254 cites W1994868799 @default.
• W2034950254 cites W1997344293 @default.
• W2034950254 cites W2003613057 @default.
• W2034950254 cites W2006003891 @default.
• W2034950254 cites W2009106439 @default.
• W2034950254 cites W2009449572 @default.
• W2034950254 cites W2014668425 @default.
• W2034950254 cites W2014839986 @default.
• W2034950254 cites W2016281653 @default.
• W2034950254 cites W2017187665 @default.
• W2034950254 cites W2018984564 @default.
• W2034950254 cites W2023039790 @default.
• W2034950254 cites W2025658574 @default.
• W2034950254 cites W2026201389 @default.
• W2034950254 cites W2027503237 @default.
• W2034950254 cites W2031150214 @default.
• W2034950254 cites W2031355550 @default.
• W2034950254 cites W2032303151 @default.
• W2034950254 cites W2033327441 @default.
• W2034950254 cites W2034197736 @default.
• W2034950254 cites W2036927039 @default.
• W2034950254 cites W2041144870 @default.
• W2034950254 cites W2041380845 @default.
• W2034950254 cites W2041392298 @default.
• W2034950254 cites W2041573974 @default.
• W2034950254 cites W2045794098 @default.
• W2034950254 cites W2046361778 @default.
• W2034950254 cites W2052889511 @default.
• W2034950254 cites W2053845854 @default.
• W2034950254 cites W2054168159 @default.
• W2034950254 cites W2054624811 @default.
• W2034950254 cites W2058448628 @default.
• W2034950254 cites W2061519575 @default.
• W2034950254 cites W2064290855 @default.
• W2034950254 cites W2065712159 @default.
• W2034950254 cites W2066529475 @default.
• W2034950254 cites W2068363907 @default.
• W2034950254 cites W2070481472 @default.
• W2034950254 cites W2075140806 @default.
• W2034950254 cites W2076000436 @default.
• W2034950254 cites W2077246828 @default.
• W2034950254 cites W2080028840 @default.
• W2034950254 cites W2081247244 @default.
• W2034950254 cites W2082957757 @default.
• W2034950254 cites W2084523269 @default.
• W2034950254 cites W2089196518 @default.
• W2034950254 cites W2089621246 @default.
• W2034950254 cites W2115200580 @default.
• W2034950254 cites W2129008942 @default.
• W2034950254 cites W2135838290 @default.
• W2034950254 cites W2140230161 @default.
• W2034950254 cites W2143856302 @default.
• W2034950254 cites W2321472385 @default.
• W2034950254 cites W2327993047 @default.
• W2034950254 cites W2521482146 @default.
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• W2034950254 doi "https://doi.org/10.1039/b907324h" @default.
• W2034950254 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19672502" @default.
• W2034950254 hasPublicationYear "2009" @default.
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