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- W2034954749 abstract "In order to detect the labiles in the aqueous solution of the benzene- and naphthoquinones, they were preliminarily transformed with the aid of the benzene sulphinic acid into stable sulphonic derivatives. Methods were developed of the chromatographic detection on paper and in a thin layer of the β-naphthol, phenol, ortho-, para-dioxybenzenes and their sulphonic derivatives with joint presence in the solution of ortho- and para-isomers of the dioxyderivatives. For the chromatographic separation of the ortho- and para-derivatives, the ability of ortho-isomers to form chelate complexes with boric acid or to precipitate with mean laed acetate salt was made use of. With the aid of the given method, the stage of the quinone formation in the course of abiogenic and biochemical (under the action of Nitella sp.) oxidation of benzene, phenol, β-naphthol, pyrocatechol, hydroquinone has been proved. Oxidation under the action of Nitella sp. leads to the formation of the dioxybenzene ortho-isomers and their derivatives." @default.
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- W2034954749 date "1975-01-01" @default.
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- W2034954749 title "Use of Thin-Layer and Paper Chromatography for Detection of Ortho- and Para-Quinones Formed in the Course of Phenol Oxidation" @default.
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- W2034954749 doi "https://doi.org/10.1002/aheh.19750030104" @default.
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