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- W2034956483 abstract "The details of the infra-red spectra over the range 200 to 1000 cm−1 are presented for eight members of the spinel series Mg(CrxAl2−x)O4 and correlated with the development of local distortions of C3v symmetry. It is shown that the frequency behaviour of two of the prominent absorption bands is described rather well by the equations given by Waldron for the modes labelled v1 and v3. Force constants k1 and k0, corresponding to unit displacements along the tetrahedral cation-oxygen and octahedral cation-oxygen bonds, respectively, are derived in a manner which allows for the presence of other interactions. Einzelheiten der Ultrarotspektren im Bereich von 200 bis 1000 cm−1 für acht Glieder der Spinellreihe Mg(CrxAl2−x)O4 werden angegeben und mit der Entstehung von örtlichen Verzerrungen mit C3v-Symmetrie in Verbindung gebracht. Es erweist sich, daß das Frequenzverhalten von zwei der starken Absorptionsbanden anhand der Gleichungen von Waldron für die Schwingungstypen v1 und v3 ziemlich gut beschrieben wird. Die Kraftkonstanten kt und ko, die den Einheitsauslenkungen in Richtung sowohl der tetraedrischen Kation-Sauerstoff- als auch der oktaedrischen Kation-Sauerstoffbindung entsprechen, lassen sich auf eine Weise ableiten, die das Vorhandensein anderer Wechselwirkungen zuläßt." @default.
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- W2034956483 title "Correlation of Infra-Red Spectra with Structural Distortions in the Spinel Series Mg(CrxAl2−x)O4" @default.
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- W2034956483 doi "https://doi.org/10.1002/pssb.2220430218" @default.
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