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- W2034961828 abstract "The use of an automated flow system coupled to a mathematically rigorous fitting routine is described for determination of the charge transfer kinetic parameters for members of the 1,4-benzodiazepines. The automated flow system offers increased productivity and reproducibility which promote investigation of the model system under a variety of experimental conditions. The values of the charge transfer parameters for reduction of the adsorbed material were determined for a range of electrode surface coverage, supporting electrolyte, and stripping parameters. The interpretation is complicated by the artifact of IR drop, which affects the magnitude of the rate parameters but not the correspondence between the experimental and optimal theoretical voltammogram. The dependence of the charge transfer coefficient α on ionic strength indicated a supporting electrolyte concentration of 1.0 M to be a proper compromise between solution resistivity and solution impurities. Values of the charge transfer coefficient and the rate constant (in reciprocal seconds, referred to −0.6 V vs. SCE) for the totally irreversible reduction of adsorbate were determined for alprazolam (0.674 ± 0.005, −3.80 ± 0.04), loprazolam (0.695 ± 0.004, −5.42 ± 0.050), midazolam (0.721 ± 0.007, −2.74 ± 0.05), and triazolam (0.750 ± 0.005, −4.10 ± 0.05) respectively, in 1.0 M acetate buffer at 25°C." @default.
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- W2034961828 date "1994-03-01" @default.
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- W2034961828 title "Determination of charge transfer kinetic parameters using an automated flow system" @default.
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- W2034961828 doi "https://doi.org/10.1016/0022-0728(93)03029-o" @default.
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