Matches in SemOpenAlex for { <https://semopenalex.org/work/W2034962835> ?p ?o ?g. }
Showing items 1 to 78 of
78
with 100 items per page.
- W2034962835 abstract "Abstract Oxidation of methyl 4,6- O -benzylidene-2-deoxy-α- D - lyxo -hexopyranoside ( 3 ) with ruthenium tetroxide gave the 3-ketone 4 in high yield. Treatment of ketone 4 with methylmagnesium iodide gave predominantly methyl 4,6- O -benzylidene-2-deoxy-3- C -methyl-α- D - xylo -hexopyranoside (5), which was converted into the 3- O -methyl derivative ( 6 ). The reaction of compound 6 with N -bromosuccinimide afforded methyl 4- O -benzoyl-6-bromo-2,6-dideoxy-3- C -methyl-3- O -methyl-α- D - xylo -hexopyranoside (7) in high yield. Compound 7 was converted, by catalytic debenzoylation and reductive debromination, into methyl α- D -arcanoside (9). Acid-catalyzed hydrolysis of glycoside 9 gave D -arcanose ( 10 ). Configurational studies support the 2,6-dideoxy-3- C -methyl-3- O -methyl- xylo -hexose structure for arcanose." @default.
- W2034962835 created "2016-06-24" @default.
- W2034962835 creator A5020350796 @default.
- W2034962835 creator A5062604704 @default.
- W2034962835 creator A5087908715 @default.
- W2034962835 date "1968-01-01" @default.
- W2034962835 modified "2023-09-28" @default.
- W2034962835 title "The synthesis of D-arcanose" @default.
- W2034962835 doi "https://doi.org/10.1039/c1968000062b" @default.
- W2034962835 hasPublicationYear "1968" @default.
- W2034962835 type Work @default.
- W2034962835 sameAs 2034962835 @default.
- W2034962835 citedByCount "3" @default.
- W2034962835 crossrefType "journal-article" @default.
- W2034962835 hasAuthorship W2034962835A5020350796 @default.
- W2034962835 hasAuthorship W2034962835A5062604704 @default.
- W2034962835 hasAuthorship W2034962835A5087908715 @default.
- W2034962835 hasConcept C106159729 @default.
- W2034962835 hasConcept C111771559 @default.
- W2034962835 hasConcept C134121241 @default.
- W2034962835 hasConcept C155647269 @default.
- W2034962835 hasConcept C161790260 @default.
- W2034962835 hasConcept C162324750 @default.
- W2034962835 hasConcept C178790620 @default.
- W2034962835 hasConcept C181199279 @default.
- W2034962835 hasConcept C185592680 @default.
- W2034962835 hasConcept C191897082 @default.
- W2034962835 hasConcept C192562407 @default.
- W2034962835 hasConcept C194671627 @default.
- W2034962835 hasConcept C2776393687 @default.
- W2034962835 hasConcept C2777738585 @default.
- W2034962835 hasConcept C2778870691 @default.
- W2034962835 hasConcept C2780073701 @default.
- W2034962835 hasConcept C94412978 @default.
- W2034962835 hasConceptScore W2034962835C106159729 @default.
- W2034962835 hasConceptScore W2034962835C111771559 @default.
- W2034962835 hasConceptScore W2034962835C134121241 @default.
- W2034962835 hasConceptScore W2034962835C155647269 @default.
- W2034962835 hasConceptScore W2034962835C161790260 @default.
- W2034962835 hasConceptScore W2034962835C162324750 @default.
- W2034962835 hasConceptScore W2034962835C178790620 @default.
- W2034962835 hasConceptScore W2034962835C181199279 @default.
- W2034962835 hasConceptScore W2034962835C185592680 @default.
- W2034962835 hasConceptScore W2034962835C191897082 @default.
- W2034962835 hasConceptScore W2034962835C192562407 @default.
- W2034962835 hasConceptScore W2034962835C194671627 @default.
- W2034962835 hasConceptScore W2034962835C2776393687 @default.
- W2034962835 hasConceptScore W2034962835C2777738585 @default.
- W2034962835 hasConceptScore W2034962835C2778870691 @default.
- W2034962835 hasConceptScore W2034962835C2780073701 @default.
- W2034962835 hasConceptScore W2034962835C94412978 @default.
- W2034962835 hasLocation W20349628351 @default.
- W2034962835 hasOpenAccess W2034962835 @default.
- W2034962835 hasPrimaryLocation W20349628351 @default.
- W2034962835 hasRelatedWork W1966911084 @default.
- W2034962835 hasRelatedWork W1971508869 @default.
- W2034962835 hasRelatedWork W1981057539 @default.
- W2034962835 hasRelatedWork W1987198325 @default.
- W2034962835 hasRelatedWork W1991101227 @default.
- W2034962835 hasRelatedWork W1996757019 @default.
- W2034962835 hasRelatedWork W1999081731 @default.
- W2034962835 hasRelatedWork W2023802477 @default.
- W2034962835 hasRelatedWork W2039865479 @default.
- W2034962835 hasRelatedWork W2052130025 @default.
- W2034962835 hasRelatedWork W2054392326 @default.
- W2034962835 hasRelatedWork W2065029502 @default.
- W2034962835 hasRelatedWork W2066947493 @default.
- W2034962835 hasRelatedWork W2069321594 @default.
- W2034962835 hasRelatedWork W2072053235 @default.
- W2034962835 hasRelatedWork W2131187782 @default.
- W2034962835 hasRelatedWork W2291569301 @default.
- W2034962835 hasRelatedWork W2313228302 @default.
- W2034962835 hasRelatedWork W2328898363 @default.
- W2034962835 hasRelatedWork W2951055434 @default.
- W2034962835 isParatext "false" @default.
- W2034962835 isRetracted "false" @default.
- W2034962835 magId "2034962835" @default.
- W2034962835 workType "article" @default.