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- W2034967592 abstract "Poly(starch-g-(1-amidoethylene)) can be formed by aqueous, free radical polymerization of 2-propenamide on lintnerized, potato starch. Initiation is by attack of cerium ions (+IV) on the D-glucopyranosyl units of starch. The reaction produces a water-soluble thickener with molecular properties of the product controlled, in part, by the gel effect induced in virtually all syntheses. Yield of product varies from 38 to 100% with yields of 90–100% being common. Products containing less than 50 wt % sidechain were found to be difficult to dissolve once they were recovered from the synthesis mixture. A sample with a design molecular weight of 0.8 × 106 and 4 grafts per backbone formed 3.9 wt % of a water-insoluble solid in the reaction mixture. The solid, which had a composition similar to that of the reaction mixture, may be the result of selective reaction within the distribution of backbone molecules." @default.
- W2034967592 created "2016-06-24" @default.
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- W2034967592 date "1987-05-05" @default.
- W2034967592 modified "2023-09-23" @default.
- W2034967592 title "Synthesis, characterization, properties, and derivatives of poly(starch-g-(1-amidoethylene)). I. Synthesis and characterization" @default.
- W2034967592 doi "https://doi.org/10.1002/app.1987.070330601" @default.
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