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• W2034971181 startingPage "1103" @default.
• W2034971181 abstract "Polydicyclopentadiene (PDCPD) is a kind of engineering plastic which possesses excellent mechanical performance. It can be prepared by dicyclopentadiene (DCPD) through Ring-opening metathesis polymerization (ROMP). In this article, a supported catalyst of WCl6-phenol on montmorillonite (MMt) was prepared. It is highly efficient, low-cost and more stable in air. PDCPD/MMt Nanocomposites were prepared by this catalyst with Et2AlCl through ROMP. The polymerization was executed in Gusmer-Decker's RIMcell Lt Machine. The d spacings of the clay in nanocomposites were monitored using X-ray diffraction (XRD), and the extent of delamination was examined by transmission electron microscopy (TEM). The XRD curves showed the expansion of clay layers due to the intercalation of WCl6-phenol catalyst into the space of MMt. The TEM micrograph showed that highly delaminated nanocomposites were achieved, even at the highest (4.0 wt% MMt) clay loading. Thermal gravimetric analysis (TGA) testing showed that thermal stabilities of nanocomposites were increased with the increase of MMt loading. The enhanced degree in the storage modulus of nanocomposites increased with the increase of MMt loading." @default.
• W2034971181 created "2016-06-24" @default.
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• W2034971181 date "2011-07-15" @default.
• W2034971181 modified "2023-10-06" @default.
• W2034971181 title "Preparation and Properties of Polydicyclopentadiene/MMt Nanocomposites Using Supported Tungsten Catalyst" @default.
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• W2034971181 doi "https://doi.org/10.1080/03602559.2011.566240" @default.
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