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- W2034974414 abstract "The oxidation of a Cu-based ternary alloy containing 30 at% Ni and 25 at% Fe has been studied at 800–900°C under low oxygen pressures. The alloy contains a mixture of a phase α rich in Cu and Ni with little Fe with a phase β rich in Fe and Ni with little Cu. The scaling kinetics show rather large deviations from the parabolic law and are much slower than those of pure Fe and of a binary Cu–25Fe alloy oxidized under the same conditions. The growth of an external layer of iron oxide is coupled to the formation of oxide particles dispersed uniformly within the alloy. The internal oxidation of Fe produces a transformation of the β phase into the Cu–Ni solid solution which becomes the matrix of the internal oxidation zone. The β phase disappears also beneath the internal oxidation front to some depth, producing a single-phase α layer. The spatial distribution of the oxide particles in the alloy is rather uniform and does not correspond to that of the two-phases in the original material, which have a largely different iron content. This is the result of a transformation of the β phase into the α phase and of the lateral diffusion of the various components through the α layer before the arrival of the internal oxidation front." @default.
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- W2034974414 date "2001-04-01" @default.
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- W2034974414 title "Oxidation of a ternary Cu–Ni–Fe alloy under low oxygen pressures at 800–900°C" @default.
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- W2034974414 doi "https://doi.org/10.1016/s0925-8388(00)01391-8" @default.
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