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- W2034982128 abstract "An experimental and theoretical study of the structure and aggregation of diphenylguanidine (DPhG) in non-polar and low-polarity solvents (CCl4, C6H6, C2HCl3 and CHCl3) was performed. Dipole moments, IR spectra and average molecular weight measurements as a function of concentration demonstrate that DPhG is strongly associated in the solvents studied. The dimerization constant in CCl4 is 192 ± 7 dm3mol−1. Experimental results and a theoretical discussion on the basis of MNDO-PM3 and -AM1 methods show that in low-polarity solvents DPhG exists in the form of an asymmetric tautomer, the same as was found in the solid-state structure." @default.
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- W2034982128 date "1996-07-01" @default.
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- W2034982128 title "Molecular structure and association of diphenylguanidine in solution" @default.
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- W2034982128 doi "https://doi.org/10.1002/(sici)1099-1395(199607)9:7<487::aid-poc805>3.0.co;2-5" @default.
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