FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2034987614> ?p ?o ?g. }

• W2034987614 endingPage "907" @default.
• W2034987614 startingPage "902" @default.
• W2034987614 abstract "Random copolymers were prepared by Candida antarctica lipase B (Novozyme-435) catalyzed copolymerization of omega-pentadecalactone (PDL) with epsilon-caprolactone (CL). Over the whole composition range PDL-CL copolymers are highly crystalline (melting enthalpy by differential scanning calorimetry, above 100 J/g; crystallinity degree by wide-angle X-ray scattering, WAXS, 60-70%). The copolymers melt at temperatures that linearly decrease with composition from that of poly(omega-pentadecalactone) (PPDL; 97 degrees C) to that of poly(epsilon-caprolactone) (PCL; 59 degrees C). The WAXS profiles of PCL and PPDL homopolymers are very similar, except for the presence in PPDL of the (001) reflection at 2theta = 4.58 degrees that corresponds to a 19.3 angstroms periodicity in the chain direction. In PDL-CL copolymers the intensity of this reflection decreases with increasing content of CL units and vanishes at 50 mol % CL, as a result of randomization of the ester group alignment and loss of chain periodicity. PDL-CL copolymers crystallize in a lattice that gradually changes from that of one homopolymer to that of the other, owing to comonomer isomorphous substitution. Cocrystallization of comonomer units is also shown by a random PDL-CL copolymer obtained in a polymerization/transesterification reaction catalyzed by C. antarctica lipase B (Novozyme-435) starting from preformed PCL and PDL monomer." @default.
• W2034987614 created "2016-06-24" @default.
• W2034987614 creator A5016921403 @default.
• W2034987614 creator A5049257620 @default.
• W2034987614 creator A5059100906 @default.
• W2034987614 creator A5062147071 @default.
• W2034987614 creator A5069930771 @default.
• W2034987614 date "2005-01-21" @default.
• W2034987614 modified "2023-10-16" @default.
• W2034987614 title "Cocrystallization of Random Copolymers of ω-Pentadecalactone and ε-Caprolactone Synthesized by Lipase Catalysis" @default.
• W2034987614 cites W1510812277 @default.
• W2034987614 cites W1529192063 @default.
• W2034987614 cites W1965501936 @default.
• W2034987614 cites W1966285398 @default.
• W2034987614 cites W1969090120 @default.
• W2034987614 cites W1970234781 @default.
• W2034987614 cites W1972275353 @default.
• W2034987614 cites W1974397062 @default.
• W2034987614 cites W1975625140 @default.
• W2034987614 cites W1996453564 @default.
• W2034987614 cites W1997742978 @default.
• W2034987614 cites W1999611688 @default.
• W2034987614 cites W2001800751 @default.
• W2034987614 cites W2003687017 @default.
• W2034987614 cites W2005039984 @default.
• W2034987614 cites W2008150408 @default.
• W2034987614 cites W2012452179 @default.
• W2034987614 cites W2017919469 @default.
• W2034987614 cites W2018760411 @default.
• W2034987614 cites W2019013712 @default.
• W2034987614 cites W2021472933 @default.
• W2034987614 cites W2024008883 @default.
• W2034987614 cites W2027931458 @default.
• W2034987614 cites W2040743016 @default.
• W2034987614 cites W2052470657 @default.
• W2034987614 cites W2055818639 @default.
• W2034987614 cites W2063633338 @default.
• W2034987614 cites W2076819001 @default.
• W2034987614 cites W2077950056 @default.
• W2034987614 cites W2085639037 @default.
• W2034987614 cites W2087577948 @default.
• W2034987614 cites W2089178668 @default.
• W2034987614 cites W378194662 @default.
• W2034987614 doi "https://doi.org/10.1021/bm0493279" @default.
• W2034987614 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/15762658" @default.
• W2034987614 hasPublicationYear "2005" @default.
• W2034987614 type Work @default.
• W2034987614 sameAs 2034987614 @default.
• W2034987614 citedByCount "122" @default.
• W2034987614 countsByYear W20349876142012 @default.
• W2034987614 countsByYear W20349876142013 @default.
• W2034987614 countsByYear W20349876142014 @default.
• W2034987614 countsByYear W20349876142015 @default.
• W2034987614 countsByYear W20349876142016 @default.
• W2034987614 countsByYear W20349876142017 @default.
• W2034987614 countsByYear W20349876142018 @default.
• W2034987614 countsByYear W20349876142019 @default.
• W2034987614 countsByYear W20349876142020 @default.
• W2034987614 countsByYear W20349876142021 @default.
• W2034987614 countsByYear W20349876142022 @default.
• W2034987614 countsByYear W20349876142023 @default.
• W2034987614 crossrefType "journal-article" @default.
• W2034987614 hasAuthorship W2034987614A5016921403 @default.
• W2034987614 hasAuthorship W2034987614A5049257620 @default.
• W2034987614 hasAuthorship W2034987614A5059100906 @default.
• W2034987614 hasAuthorship W2034987614A5062147071 @default.
• W2034987614 hasAuthorship W2034987614A5069930771 @default.
• W2034987614 hasConcept C121332964 @default.
• W2034987614 hasConcept C15920480 @default.
• W2034987614 hasConcept C166940927 @default.
• W2034987614 hasConcept C178790620 @default.
• W2034987614 hasConcept C181199279 @default.
• W2034987614 hasConcept C185592680 @default.
• W2034987614 hasConcept C188027245 @default.
• W2034987614 hasConcept C192562407 @default.
• W2034987614 hasConcept C2779542420 @default.
• W2034987614 hasConcept C2779697368 @default.
• W2034987614 hasConcept C2780672802 @default.
• W2034987614 hasConcept C2781111393 @default.
• W2034987614 hasConcept C39519442 @default.
• W2034987614 hasConcept C44228677 @default.
• W2034987614 hasConcept C46275449 @default.
• W2034987614 hasConcept C521977710 @default.
• W2034987614 hasConcept C8010536 @default.
• W2034987614 hasConcept C97355855 @default.
• W2034987614 hasConceptScore W2034987614C121332964 @default.
• W2034987614 hasConceptScore W2034987614C15920480 @default.
• W2034987614 hasConceptScore W2034987614C166940927 @default.
• W2034987614 hasConceptScore W2034987614C178790620 @default.
• W2034987614 hasConceptScore W2034987614C181199279 @default.
• W2034987614 hasConceptScore W2034987614C185592680 @default.
• W2034987614 hasConceptScore W2034987614C188027245 @default.
• W2034987614 hasConceptScore W2034987614C192562407 @default.
• W2034987614 hasConceptScore W2034987614C2779542420 @default.
• W2034987614 hasConceptScore W2034987614C2779697368 @default.
• W2034987614 hasConceptScore W2034987614C2780672802 @default.
• W2034987614 hasConceptScore W2034987614C2781111393 @default.
• W2034987614 hasConceptScore W2034987614C39519442 @default.

• next