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- W2034992804 abstract "A pneumatic nebulizer interface for capillary electrophoresis (CE) and inductively coupled plasma mass spectrometry (ICPMS) is reported. The interface is constructed using a high-efficiency cross-flow micronebulizer (HECFMN) and has the following features. (1) Makeup solutions can be fed to the interface by nebulizer self-aspiration and liquid gravity pressurization. (2) The liquid dead volume of the interface is ∼65 nL, much smaller than those (200−2500 nL) reported for other interfaces. (3) The interface can be stably operated at a liquid flow rate down to 5 μL/min with a high analyte transport efficiency up to 95% to the plasma and (4) does not induce noticeable laminar flow in the CE capillary at typical nebulizer gas flow rates of 0.8−1.2 L/min. Because of these features, baseline resolution of 10 lanthanides with a CE−ICPMS system using the HECFMN interface is achieved, and detection limits and peak asymmetry are 0.05−1 μg/L and 0.93−1.23, respectively, improved significantly over those reported previously for a CE−ICPMS system using a high-efficiency nebulizer interface. Peak precision for the 10 lanthanides is in the range of 6.2−12.3% RSD (N = 5). Peak widths are from 9.1 s for 139La to 17.9 s for 175Lu. The effects of nebulizer gas flow rate, makeup solution flow rate, and spray chamber volume on CE−ICPMS signal intensity and separation are also evaluated for the HECFMN interface by the separation of Cr3+ and Cr2O72-." @default.
- W2034992804 created "2016-06-24" @default.
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- W2034992804 date "2001-11-17" @default.
- W2034992804 modified "2023-10-10" @default.
- W2034992804 title "A High-Efficiency Cross-Flow Micronebulizer Interface for Capillary Electrophoresis and Inductively Coupled Plasma Mass Spectrometry" @default.
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- W2034992804 doi "https://doi.org/10.1021/ac010595w" @default.
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