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- W2034993660 abstract "Pyrido[4,3,2-kl]acridines represent a new class of heterocycles, isomers of marine alkaloids. The 7H-pyrido[4,3,2-kl]acridine reacts as an electron rich heterocycle, and in particular via electrophilic substitution such as H/D exchange and the Vilsmeier−Haack reaction. The reaction is fully regioselective and gives the corresponding 6-substituted derivatives. The pyrido[4,3,2-kl]acridin-4-one reacts with amines and thiol, via 1,4-Michael addition to give the 6-amino or 6-thio analogues in a very efficient way. Molecular calculations account for the observed regioselectivity." @default.
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- W2034993660 date "2004-10-09" @default.
- W2034993660 modified "2023-09-28" @default.
- W2034993660 title "Reactivity of Pyrido[4,3,2-<i>kl</i>]acridines: Regioselective Formation of 6-Substituted Derivatives" @default.
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- W2034993660 doi "https://doi.org/10.1021/jo0487855" @default.
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