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- W2035031976 abstract "Controlled-potential reductions of primary alkyl halides (RX, where X = Cl, Br, or I) have been carried out at smooth and at platinized platinum electrodes in dimethylformamide containing tetramethylammonium tetrafluoroborate (TMABF 4 ) under super-dry conditions ([H 2 O] 96%). On the other hand, electrolysis of 1-iodobutane at -2.2 V vs. SCE and at a platinized platinum cathode gives 1-butene and butane in essentially a 1:1 ratio. These observations, buttressed by additional data derived from scanning electron microscopy and cyclic voltammetry, can be explained by the formation of an ionometallic layer, (Pt - n, TMA TMABF 4 ), on the surface of the platinum cathode at a potential for which there is concomitant reduction both of RX and of traces of water (to produce hydroxide ions within the layer). Thereafter, the resulting surface-modified platinum electrode (with a strongly basic character) acts catalytically via an E2 process to form an alkene from a primary alkyl halide." @default.
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- W2035031976 date "2004-01-01" @default.
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- W2035031976 title "Electrochemical Conversion of Primary Alkyl Halides to Alkenes at Platinum Cathodes" @default.
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- W2035031976 doi "https://doi.org/10.1149/1.1636179" @default.
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