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- W2035066602 abstract "Abstract Samples of poly(decylmethacrylate)s (PDMA) of a narrow molecular weight distribution were characterized by means of light-scattering, osmotic pressure, intrinsic viscosity and gelpermeation chromatography. The Kuhn-Mark-Houwink equation for molecularly uniform PDMA in THF at 25°C was calculated to be log [η] (ml/g) = −2.67 + 0.80 log M (g/mol). The following Θ-solvents were found: 2-propanol, 2-propylacetate, 1-butanol and 1-pentanol. The molecular weight dependence of the demixing behaviour yields a Θ-temperature of 9.6°C for 1-pentanol and of 37.4°C for 1-butanol. Flow curves were measured in various solvents of different thermodynamic quality. A first valuation of the observed non-Newtonian behaviour is given." @default.
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- W2035066602 date "1983-03-01" @default.
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- W2035066602 title "Solution properties of poly(decylmethacrylate)s" @default.
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- W2035066602 doi "https://doi.org/10.1016/0254-0584(83)90036-6" @default.
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