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- W2035100229 abstract "New iron-based intercalation superconductors Ax(C2H8N2)yFe2−zSe2 (A = Li, Na) with Tc = 45 K have successfully been synthesized via intercalation of dissolved alkaline metal in ethylenediamine. The c-axis lengths of Ax(C2H8N2)yFe2−zSe2 (A = Li, Na) are 20.74(7) Å and 21.9(1) Å, respectively, and are about 50% larger than that of KxFe2Se2, indicating that not only alkaline metal but also ethylenediamine is intercalated between the Se–Se layers of FeSe. It seems that the high-Tc of Ax(C2H8N2)yFe2−zSe2 (A = Li, Na) is caused by the possible two-dimensional electronic structure due to the large c-axis length. Through the post-annealing in an evacuated glass tube, it has been found that Tc decreases with increasing post-annealing temperature and that deintercalation of EDA from the as-intercalated sample takes place at low temperatures below 250 °C." @default.
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- W2035100229 date "2014-09-01" @default.
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- W2035100229 title "Synthesis and post-annealing effects of alkaline-metal-ethylenediamine-intercalated superconductors A(C2H8N2) Fe2−Se2 (A= Li, Na) with Tc= 45 K" @default.
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- W2035100229 doi "https://doi.org/10.1016/j.physc.2014.01.007" @default.
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