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- W2035123432 abstract "Chiral N-sulfinyl ureas have been developed as catalysts for an asymmetric aza-Henry reaction. Addition of nitroalkanes 3 to both aromatic and aliphatic N-Boc imines 2 in the presence of organocatalyst 1 (10 mol%) and i-Pr2NEt (50 mol%) gives protected nitroamines 4 in high yields, syn-diastereoselectivities, and enantioselectivities. The authors present examples of enantioselective hydrogen-bonding-catalyzed additions to aliphatic N-Boc imines." @default.
- W2035123432 created "2016-06-24" @default.
- W2035123432 date "2008-03-19" @default.
- W2035123432 modified "2023-09-25" @default.
- W2035123432 title "A New Class of Hydrogen-Bonding Catalysts: N-Sulfinyl Ureas" @default.
- W2035123432 doi "https://doi.org/10.1055/s-2008-1042829" @default.
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