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- W2035134857 abstract "A theoretical study was made of the effect of the form and with of various relaxation time spectra — Cole-Cole, Cole-Davidson, Fröhlich “semi-empirical” distributions on the dependence of relative depolarization of luminescence Y ( T / ν ) (where T is the absolute temperature, and ν — solvent viscosity). Relations were derived of Y / T / ν for all spectrum types studied with different spectrum width parameters. It was shown that the relations of polarization luminescence (PL) depend largely on the form of the relaxation time spectrum. For the broad symmetrical Cole-Cole distribution ( Y / T / ν ) has no linear sections over the entire range of variation of T / ν , while for the asymmetrical Cole - Davidson distribution and finite “box” type Fröhlich distribution values of Y ( T / ν ) go outside the linear asymptote with high values of T / ν . For all types of distribution a widening of the spectrum increases the curvature of T / T / ν . From a comparison of theory and experiment on PL of macromolecules with luminescent tracers parameters of spectrum width were evaluated, which may be used to describe experimental results. These parameters appeared to be close to parameters obtained from investigations of dielectric relaxation of polymer solutions of the same class." @default.
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- W2035134857 date "1976-01-01" @default.
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- W2035134857 title "Relaxation time spectra and relations of polarization luminescence of macromolecules with luminescent tracers" @default.
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- W2035134857 doi "https://doi.org/10.1016/0032-3950(76)90433-0" @default.
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