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- W2035143203 abstract "Die alkoholat-induzierte Chlorwasserstoff-Abspaltung aus Styrylchlorid betätigt möglicherweise drei verschiedene Reaktionsmechanismen nebeneinander: E2, E1cb und E1cb-HBA (ein modifizierter Elcb-Mechanismus). Diese Schlußfolgerung stützt sich auf die folgenden Kriterien: H/D-Austausch, Isotopeneffekte, Reaktionsordnung sowie relative Eliminierungs-geschwindigkeiten in Abhängigkeit von der Konfiguration des Substrates (cis oder trans) und der Art der Base (NaOC2H5 oder KOC(CH3)3). Base-induced Eliminations, IV Reaction of Metal Alcoholates with cis- and trans-Styryl Chloride Possibly the dehydrochlorination of styryl chloride under the influence of an alcoholate occurs by three different, competing mechanisms: E2, Elcb and Elcb-HBA (a modification of the Elcb-mechanism). This conclusion is in accord with the following criteria: H/D-exchange, isotope effects, order of reaction and relative reaction rates as a function of substrate configuration (cis or trans) as well as nature of base (NaOC2H5 or KOC(CH3)3)." @default.
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- W2035143203 title "Basen‐induzierte Eliminierungen, IV Die Einwirkung von Metall‐alkoholaten auf <i>cis</i> ‐ und <i>trans</i> ‐Styrylchlorid" @default.
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