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• W2035150207 abstract "The dithioformato complexes RuCl(P ∼ O)3(η2CH) (2ab) and RuCl(P ⋒ O(P ∼ O)(η2-S2CH) (3ab) are accessible by insertion of CS2 into the RuH bond of the (ether-phosphine)(hydrido)ruthenium complexes RuCl(P ⋒ O)(P ∼ O)2 (1a,b) [P ∼ O = η1(P)-coordinated, P ⋒ O = η2 (O,P)-chelated; O,P = diphenyl(2-methoxyethyl)phosphone (a), (1,3-dioxan-2-methyl) diphenylphosphine (b)]. Treatment of 2a, 3a and 2b, 3b with carbon monoxide in CH2Cl2 results in the formation of the carbonyl complexes Ru(CO)Cl(P ∼ O)2(η2S2CH) (4a,b). The structures of 2a and 4a were determined by single crystal X-ray diffraction analyses. Crystal data for 2a: space group Pca21 with a = 17.578(4) A, b = 14.215(3) A, c = 17.934(4) A, V = 4481(2) A3, Z = 4. The structure was refined to R = 0.037, wR = 0.082. Crystal data for 4a: space group P1/n with a = 12.009(2) A, b = 17.143(4) A, c = 16.510(4) A, β = 107.92(2)°, V = 3234(1) A3, Z = 4. The structure was refined to R = 0.035, wR = 0.087. 1a,b react with phenylacetylene to give the acetylide complexes RuCl(P ⋒ O(P ∼ O)2(CCPh) 5a,b with evulition of dihydrogen. Carbonylation of 5a yields the cis-η1(P-coordinated complex RuCl(P ⋒ O(P ∼ O)2(CCPh) (6). If chloride is abstracted from Ru(CO) Cl(P ∼ O)2(η2-S2CH) (4a) with AgBF4 in THF the P ⋒ O-chelated complex Ru(CO) Cl(P ∼ O)2(η2-S2CH][BF4] (4) is obtained. Upon reaction of 7 with PhCCH the RuO bond is cleaved and instead of an η1-vinylidene species the acetylide complex Ru(CO) Cl(P ∼ O)2(η2-S2CH) (8) is formed." @default.
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• W2035150207 title "Reactions of ether-phosphine ruthenium hydride complexes with carbon disulfide and phenylacetylene: crystal structures of Ru(CO) Cl(P ∼ O)3(η2-S2CH and Ru(CO) Cl(P ∼ O)2(η2-S2CH)" @default.
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• W2035150207 doi "https://doi.org/10.1016/0022-328x(95)05950-t" @default.
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