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• W2035155116 abstract "The introduction of Mn ions into Cu(I)-ZSM-5 was found to lead to an enhancement of the photocatalytic activity for the direct decomposition of N2O into N2 and O2 at 298 K. Various in-situ techniques such as ESR, photoluminescence, XAFS as well as a combination of CO-FT-IR and CO-TPD measurements revealed that the accommodation of Mn ions within ZSM-5 zeolite cavities significantly affects the location sites of the ion-exchanged Cu(II) ions as well as the local structure of the Cu(I) ion species formed by evacuation at high temperatures. Moreover, the introduction of Mn ions into ZSM-5 led to an increase in the amount of 3-coordinated Cu(I) species at the main channel of the zeolite, playing a major role as the active species for the photocatalytic decomposition of N2O into N2 and O2." @default.
• W2035155116 created "2016-06-24" @default.
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• W2035155116 date "2006-02-09" @default.
• W2035155116 modified "2023-10-12" @default.
• W2035155116 title "Investigations on the Effect of Mn Ions on the Local Structure and Photocatalytic Activity of Cu(I)−ZSM-5 Catalysts" @default.
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• W2035155116 doi "https://doi.org/10.1021/jp055604+" @default.
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