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- W2035156728 abstract "Polarographische und cyclovoltammetrische Messungen an den N,N-disubstituierten Thioamiden 1–4 im aprotonischen Medium zeigen, daß die Aufnahme von Elektronen und das Verhalten der gebildeten Radikalanionen wesentlich von den Substituenten im Thioacylrest und am Stickstoff abhängen. – Bei präparativen Elektrolysen in Gegenwart von Alkylierungsmitteln entstehen in guten Ausbeuten die α-Amino-thioether 8–13. Die entsprechenden α-Amino-silylthioether 23 werden dagegen zu α-(Trimethylsilyl)benzylaminen 24 weiterreduziert. Ist Sauerstoff und Ethylhalogenid zugegen, so erhält man aus den Thioamiden 2a und c Thiobenzoesäure-S-ethylester (27). Electroreduction of Organic Compounds, 6. Electroreduction of N,N-Disubstituted Thioamides in the Presence of Electrophiles Electron-uptake by the N,N-disubstituted thioamides 1–4 in aprotic medium and the behaviour of their radical anions depend substantially on the nature of the thioacyl group and the nitrogen substituents as shown by polarographic and cyclovoltammetric measurements. – Good yields of the α-amino thioethers 8–13 are obtained by preparative electroreduction in the presence of alkylating agents. The corresponding α-amino-silyl thioethers 23 are further reduced to α-(trimethylsilyl)benzylamines 24. In the presence of oxygen and ethyl halide S-ethyl thiobenzoate (27) is formed from 2a or c." @default.
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- W2035156728 date "1985-12-01" @default.
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- W2035156728 title "Elektroreduktion organischer Verbindungen, 6. ElektroreduktionN,N-disubstituierter Thioamide in Gegenwart von Elektrophilen" @default.
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- W2035156728 doi "https://doi.org/10.1002/cber.19851181215" @default.
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