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- W2035158001 abstract "Abstract A water-in-toluene microemulsion stabilized by the polymerizable surfactant didecyldimethylammonium methacrylate has been used to form polyelectrolyte particles. The microemulsion was photopolymerized using AIBN as the initiator, resulting in aggregates having hydrodynamic diameters of ∼11 nm, starting with 5–6 nm initial nanodroplets with and without added sodium methacrylate (NaMA). The dried latexes have a diameter of 6 nm up to a [NaMA]/[surfactant] mole ratio ( R ) of 0.5, but 12 nm for R =1.0. For R =0–0.5, the maximum degree of polymerization was 50%, but it was 83% for R =1.0. The polydispersity decreases with increasing R , while the film-forming tendency of the latexes increases." @default.
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- W2035158001 date "1999-07-01" @default.
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- W2035158001 title "Polymerization of methacrylate in a W/O microemulsion stabilized by a methacrylate surfactant" @default.
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