FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2035162803> ?p ?o ?g. }

• W2035162803 endingPage "184" @default.
• W2035162803 startingPage "175" @default.
• W2035162803 abstract "Reactions of the tertiary phosphines PMe3, PEt3, PMe2Ph, PMePh2 and PPh3 with Co(NO2)2 are described. For PMe3 and PMe2Ph, five-coordinate Co(NO2)2(PR3)3 complexes (1,2) are isolated. With PEt3, only Co(NO)(NO2)2(PEt3)2 (3) is obtained, whereas the Co(NO)(NO2)2(PMe3)2 (4) and Co(NO)(NO2)2(PMe2Ph)2 (5) analogs result from the reaction of 1 and 2 with NO gas. From EPR measurements, the electronic structures of 1 and 2 are found to correspond to low-spin d7 square-pyramidal complexes in the solid state. Compounds 3, 4 and 5 are pseudo-octahedral Co(III) species containing three different nitrogen oxide ligands, namely NO, O-bonded NO2 and N-bonded NO2. The reactions of 1 and 2 with CO are solvent dependent: in methanol Co(NO)(CO)(PMe3)2 is obtained, but in toluene a mixture of 5 and Co(NO)2(NO2)(PMe2Ph) precipitates. Co(NO)(NO2)2(PEt3)2 reacts with O2 to form the cobalt(II) complex Co(NO3)2(OPEt3)2 shown by X-ray diffraction to be a distorted octahedron with bidentate nitrate ligands and two OPEt3 ligands in cis positions." @default.
• W2035162803 created "2016-06-24" @default.
• W2035162803 creator A5027967605 @default.
• W2035162803 creator A5066002043 @default.
• W2035162803 date "1972-07-01" @default.
• W2035162803 modified "2023-09-28" @default.
• W2035162803 title "Some aspects of the chemistry of phosphine-cyanide complexes of transition metals" @default.
• W2035162803 cites W1969846255 @default.
• W2035162803 cites W1969958105 @default.
• W2035162803 cites W1973112125 @default.
• W2035162803 cites W1973723982 @default.
• W2035162803 cites W1976256515 @default.
• W2035162803 cites W1977717826 @default.
• W2035162803 cites W1982741460 @default.
• W2035162803 cites W1983108745 @default.
• W2035162803 cites W1987077226 @default.
• W2035162803 cites W1995079027 @default.
• W2035162803 cites W1998421195 @default.
• W2035162803 cites W1999708484 @default.
• W2035162803 cites W2009158897 @default.
• W2035162803 cites W2015784886 @default.
• W2035162803 cites W2016689986 @default.
• W2035162803 cites W2021346728 @default.
• W2035162803 cites W2027564561 @default.
• W2035162803 cites W2029150364 @default.
• W2035162803 cites W2035165489 @default.
• W2035162803 cites W2048762803 @default.
• W2035162803 cites W2050490616 @default.
• W2035162803 cites W2062294712 @default.
• W2035162803 cites W2063004074 @default.
• W2035162803 cites W2074262677 @default.
• W2035162803 cites W2078798561 @default.
• W2035162803 cites W2103760003 @default.
• W2035162803 cites W2234865995 @default.
• W2035162803 cites W2936580420 @default.
• W2035162803 doi "https://doi.org/10.1016/s0010-8545(00)80066-1" @default.
• W2035162803 hasPublicationYear "1972" @default.
• W2035162803 type Work @default.
• W2035162803 sameAs 2035162803 @default.
• W2035162803 citedByCount "11" @default.
• W2035162803 crossrefType "journal-article" @default.
• W2035162803 hasAuthorship W2035162803A5027967605 @default.
• W2035162803 hasAuthorship W2035162803A5066002043 @default.
• W2035162803 hasConcept C106773901 @default.
• W2035162803 hasConcept C115624301 @default.
• W2035162803 hasConcept C121332964 @default.
• W2035162803 hasConcept C155647269 @default.
• W2035162803 hasConcept C161790260 @default.
• W2035162803 hasConcept C178516000 @default.
• W2035162803 hasConcept C178790620 @default.
• W2035162803 hasConcept C179104552 @default.
• W2035162803 hasConcept C185592680 @default.
• W2035162803 hasConcept C187961010 @default.
• W2035162803 hasConcept C198819137 @default.
• W2035162803 hasConcept C2777716191 @default.
• W2035162803 hasConcept C2778142098 @default.
• W2035162803 hasConcept C2778455166 @default.
• W2035162803 hasConcept C2780471494 @default.
• W2035162803 hasConcept C46141821 @default.
• W2035162803 hasConcept C515602321 @default.
• W2035162803 hasConcept C71240020 @default.
• W2035162803 hasConcept C8010536 @default.
• W2035162803 hasConcept C92840921 @default.
• W2035162803 hasConceptScore W2035162803C106773901 @default.
• W2035162803 hasConceptScore W2035162803C115624301 @default.
• W2035162803 hasConceptScore W2035162803C121332964 @default.
• W2035162803 hasConceptScore W2035162803C155647269 @default.
• W2035162803 hasConceptScore W2035162803C161790260 @default.
• W2035162803 hasConceptScore W2035162803C178516000 @default.
• W2035162803 hasConceptScore W2035162803C178790620 @default.
• W2035162803 hasConceptScore W2035162803C179104552 @default.
• W2035162803 hasConceptScore W2035162803C185592680 @default.
• W2035162803 hasConceptScore W2035162803C187961010 @default.
• W2035162803 hasConceptScore W2035162803C198819137 @default.
• W2035162803 hasConceptScore W2035162803C2777716191 @default.
• W2035162803 hasConceptScore W2035162803C2778142098 @default.
• W2035162803 hasConceptScore W2035162803C2778455166 @default.
• W2035162803 hasConceptScore W2035162803C2780471494 @default.
• W2035162803 hasConceptScore W2035162803C46141821 @default.
• W2035162803 hasConceptScore W2035162803C515602321 @default.
• W2035162803 hasConceptScore W2035162803C71240020 @default.
• W2035162803 hasConceptScore W2035162803C8010536 @default.
• W2035162803 hasConceptScore W2035162803C92840921 @default.
• W2035162803 hasIssue "1-2" @default.
• W2035162803 hasLocation W20351628031 @default.
• W2035162803 hasOpenAccess W2035162803 @default.
• W2035162803 hasPrimaryLocation W20351628031 @default.
• W2035162803 hasRelatedWork W2025360487 @default.
• W2035162803 hasRelatedWork W2062439442 @default.
• W2035162803 hasRelatedWork W2086624232 @default.
• W2035162803 hasRelatedWork W2158006654 @default.
• W2035162803 hasRelatedWork W2912599806 @default.
• W2035162803 hasRelatedWork W2952408798 @default.
• W2035162803 hasRelatedWork W2952562299 @default.
• W2035162803 hasRelatedWork W4252923152 @default.
• W2035162803 hasRelatedWork W1973450372 @default.
• W2035162803 hasRelatedWork W2950780349 @default.
• W2035162803 hasVolume "8" @default.

• next