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• W2035173655 abstract "The reaction of 5, 6, 7, 8-tetrakis(methylene)bicyclo[2.2.2.]oct-2-ene (1) with Fe29CO)9 yields under various conditions the exo and endo-tetrahaptotri-carbonyliron complexes(2 and3) and the endo, exobis(tetrahaptotricarbonyliron) complex (4); with Fe(CO)39benzalacetone), 2 and the bis(exo-tetrahapto-tricarbonyliron) complex (5) are obtained. The little ligand reacts with M(CO)3(CH3CN)3 (M = Mo, W) giving respectively the hezahapto-tricarbonyl-molybdenum and -tugnsten complex (6, 7). Coordination of all five double bonds of the pentaene is achieved by reacting 2 with Mo9CO)3(CH3CN)3 giving the exo-tetrahapto-tricarbonyliron-hexahapto-tricarbonylmolybdenum complex (8). The structures of complexes 3–8 in solution were deduced from their NMR data and the molecular structure of 2 was determined by X-ray crystallography. The Fe(CO)3 group is in th eexo position with respect to the roof-shaped pentaene. The ligand is bound through one s-cis-butadiene group to two basal positions of a tetragonal pyramidal Fe(CO)3X2 moiety. Hydrogen atom positions were refined in the last cycles (final residual R = 0.023). H(Z) atoms deviate from the diene plane of the coordinated diene away from the metal by ∼42°, whereas H(E) atoms deviate towards the metal by ∼16°. Hybridization at the “inner” carbon atoms as well as at the carbon atoms of the other three double bonds does not differ significantly from sp2. Kinetic study of the cycloaddition reaction of a dienophile to the free 1, 3-diene system of the monometallic complexes shows that the rate with respect to that of the free ligand is not much affected by the presence of the metal." @default.
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• W2035173655 date "1979-01-01" @default.
• W2035173655 modified "2023-09-27" @default.
• W2035173655 title "Iron, molybdenum and tungsten carbonyls of 5, 6, 7, 8-tetrakis(methylene)bicyclo[2.2.2.] oct-2-ene. Crystal and molecular structure of (C12H12)Fe(CO)3" @default.
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• W2035173655 doi "https://doi.org/10.1016/s0020-1693(00)89387-1" @default.
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