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- W2035197250 abstract "1-Hexene polymerization was conducted by [t-BuNSiMe2(3,6-t-Bu2Flu)]TiMe2 (1) using trialkylaluminum-free modified methylaluminoxane (dMMAO) as a cocatalyst in toluene. The system produced living syndiotactic poly(1-hexene) with high turnover frequency of propagation (TOF, 98 s−1) at 0 °C. The propagation rate was increased linearly against the 1-hexene concentration, which indicates that the first-order dependence of the propagation rate on monomer concentration. Polymerizations of 1-octene, 1-decene and 1-dodecene were also conducted for investigating the effect of chain length of 1-alkene on propagation rate by means of the livingness of this system. The propagation rate decreased according to the chain length until 1-decene but almost unchanged in longer 1-alkene: TOF, 1-octene (62 s−1)>1-decene (32 s−1) ≈ 1-dodecene (31 s−1)." @default.
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- W2035197250 date "2009-09-01" @default.
- W2035197250 modified "2023-09-26" @default.
- W2035197250 title "Highly Active Syndiospecific Living Polymerization of Higher 1-Alkene with <i>ansa</i> -Fluorenylamidodimethyltitanium Complex" @default.
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- W2035197250 doi "https://doi.org/10.1002/marc.200900413" @default.
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