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- W2035202486 abstract "We combine surface-enhanced Raman spectroscopy (SERS) and tools of computational chemistry with scanning electron, atomic force, and photoemission electron microscopy to investigate the origin of Raman scattering of 4,4′-biphenyldicarboxylic acid adsorbed as 4,4′-biphenyldicarboxylate on two different silver substrates. The first consists of a 100 nm deep cylindrical aperture embedded in an array of cylindrical nanoholes featuring an average diameter of 350 nm and a periodicity of 700 nm. The second is a nanojunction formed between a 100 nm silver nanoparticle and a flat silver surface. We find that the underlying background signal in the SERS spectra collected from the former strongly resemble the SERS spectra of the nanosphere-featuring substrate, engineered to operate at the quantum limit. Our analysis of a series of SERS spectra consecutively collected from one nanocylinder suggests that the optical response of a single molecule can be extracted, with its brightest Raman-active mode enhanced by a factor of 2.2 × 106." @default.
- W2035202486 created "2016-06-24" @default.
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- W2035202486 date "2013-03-28" @default.
- W2035202486 modified "2023-09-27" @default.
- W2035202486 title "The Origin of Surface-Enhanced Raman Scattering of 4,4′-Biphenyldicarboxylate on Silver Substrates" @default.
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- W2035202486 doi "https://doi.org/10.1021/jp401026x" @default.
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