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- W2035344544 abstract "The near and far i.r. spectra of C6H5TlCl2 and C6H5TlBr2 were recorded in the region 4000-20 cm−1 in the solid phase. A normal coordinate analysis (NCA) was carried out assuming C2ν symmetry for both the molecules. Some new fundamental frequencies were observed and assigned. Some of the assignments proposed earlier for C6H5TlCl2 have been revised in the light of the NCA. A comparative study of the vibrational analysis and NCA of the above molecules along with those of C6H5TlF2 is presented. Twenty-eight symmetrized principal and seven interaction force constants were found to reproduce the observed frequencies well with an average error of nearly 2.0% with a reasonably good potential energy distribution and standard deviations in the calculated frequencies and the force constants." @default.
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- W2035344544 date "1985-01-01" @default.
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- W2035344544 title "Vibrational spectra and normal coordinate analysis of phenylthallium dihalides—II. Phenylthallium dichloride (C6H5TlCl2) and phenylthallium dibromide (C6H5TlBr2)" @default.
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- W2035344544 doi "https://doi.org/10.1016/0584-8539(85)80136-7" @default.
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