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- W2035366287 abstract "The release behavior of fluorescent dyes, oligo DNAs and spherical proteins from self-assembled organic nanotubes having 7–9 nm inner diameters has been studied in terms of novel nanocontainers with high-axial ratios. Both much smaller inner diameters and asymmetric inner and outer surfaces are characteristic of the nanotubes. The acid-dissociation constant (pKa) of the amino groups located at the inner surface and the thermal phase transition temperature (Tg–l) of the nanotube were evaluated based on the pH titration and variable-temperature circular dichroism (CD) spectroscopic experiments, respectively. Each guest was slowly released from both open ends of the nanotube under weak alkaline conditions (pH 8.5), as a result of the decrease in electrostatic attraction between the inner surface and the guests. Elevated temperatures above the obtained Tg–l converted the monolayer membrane of the nanotube from a solid state to a fluid one, promoting the remarkably fast release of the guests. The unique release properties of the nanotube as a nanocontainer with two terminal open ends were compared with those of liposomes that posses a closed hollow space covered with fluid bilayer membranes." @default.
- W2035366287 created "2016-06-24" @default.
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- W2035366287 date "2008-01-01" @default.
- W2035366287 modified "2023-10-17" @default.
- W2035366287 title "Controllable biomolecule release from self-assembled organic nanotubes with asymmetric surfaces: pH and temperature dependence" @default.
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- W2035366287 doi "https://doi.org/10.1039/b803742f" @default.
- W2035366287 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32907162" @default.
- W2035366287 hasPublicationYear "2008" @default.
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