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- W2035367008 abstract "The optical properties of Cu atoms deposited in the underpotential region from electrolytic solution onto a polycrystalline Pt electrode have been studied by differential reflectance spectroscopy. Spectra of the normalized reflectance change (ΔRR) have been obtained in the photon energy range between 1.5 and 5.5 eV for p- and s-polarized light as a function of coverage θ and angle of incidence ϑ1. Evaluation of the adsorbate optical constants by a simple 3-phasemodel reveals three absorption bands in the range studied, one of them being strongly angular dependent. From an assignment of these transitions the positions of the 3d-, 4s- and 4p-derived levels in the energy level diagram of the Cu adatom is determined. As expected these levels are considerably shifted and broadened in comparison to their unperturbed atomic counterparts. Optical evidence for the occurrence of a structural change in the adsorbate layer at about θ = 0.6 is also presented." @default.
- W2035367008 created "2016-06-24" @default.
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- W2035367008 date "1977-05-01" @default.
- W2035367008 modified "2023-09-26" @default.
- W2035367008 title "Optical properties and electronic structure of copper atoms adsorbed on a platinum electrode" @default.
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- W2035367008 doi "https://doi.org/10.1016/0039-6028(77)90072-3" @default.
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