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• W2035392710 abstract "Based on enantioselective proline-catalyzed reactions between NH-iminotrifluoroethylphosphonate and acetone, an effective synthetic approach to both enantiomers of α-amino-α-trifluoromethyl-γ-oxobutylphosphonate was developed. The synthetic potential of these novel chiral synthons was illustrated by their cyclocondensation reactions with 4-chlorophenylisocyanate or 2,5-dimethoxytetrahydrofuran to afford the first representatives of phosphorylated 3,4-dihydropyrimidin-2-ones or 3H-pyrrolizines, incorporating pharmacophoric optically active fragments of phosphonotrifluoroalanine." @default.
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• W2035392710 date "2014-09-01" @default.
• W2035392710 modified "2023-10-10" @default.
• W2035392710 title "Asymmetric synthesis of phosphonotrifluoroalanine derivatives via proline-catalyzed direct enantioselective CC bond formation reactions of NH trifluoroacetimidoyl phosphonate" @default.
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• W2035392710 doi "https://doi.org/10.1016/j.tetasy.2014.07.007" @default.
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