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• W2035400525 startingPage "271" @default.
• W2035400525 abstract "The reaction of 1,2-dimethyl-2,3,4,5-tetraphenylstannacyclopentadiene [(Ph4C4)SnMe2] with AuCl3(tht) (tht=tetrahydrothiophen) leads to the auracyclopentadiene complexes [(Ph4C4)AuCl(tht)] or [(Ph4C4)AuCl]2, which react with Tl(acac) to give the complex [(Ph4C4)Au(acac)]. Reaction of the latter with protonated ligands (HXL) or (H2X2L2) leads to the formation of neutral mononuclear or binuclear complexes of the types [(Ph4C4)Au(XL)] (where XL is a monoanionic bidentate ligand) or [(Ph4C4)Au(X2L2)Au(Ph4C4)] (where X2L2 is a dianionic tetradentate ligand). Reaction of the acetylacetonate complex with ammonium or pyridinium salts (LH+X-) gives the mononuclear neutral complexes [(Ph4C4)Au(X)(L)] (X = CH3COO or CF3COO; L = NH3 or py) or the cationic complexes [(Ph4C4)AuLL′]X when X is an anion with poor coordinating capacity (X = ClO4 or BF4) and the reaction is carried out in the presence of a neutral ligand (L′ = PPh3)." @default.
• W2035400525 created "2016-06-24" @default.
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• W2035400525 creator A5047522775 @default.
• W2035400525 creator A5070273788 @default.
• W2035400525 date "1981-04-01" @default.
• W2035400525 modified "2023-10-18" @default.
• W2035400525 title "New ways for the preparation of heterocyclic gold(III) complexes" @default.
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• W2035400525 doi "https://doi.org/10.1016/s0022-328x(00)93597-6" @default.
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